寮犳案鍜岀瀛愬叡浠疯搴旂敤锛?span lang="EN-US">30锛?/span>  

寮犳案鍜岀數璐熸€с€佽矾鏄撳＋寮哄害 棰勭ずBZO鎬ц兘鏀硅繘

鍩轰簬寮犳案鍜岀瀛愬叡浠疯鍙婄數璐熸€с€佽矾鏄撳＋閰稿己搴﹀拰绂诲瓙婵€鍖栧姏閿弬鏁版柟娉?span lang="EN-US">[16] [17]锛岀獊灏兼柉鑻忓痉澶у鍜屼腑澶ぇ瀛︾殑R.B.Hadjtahar鍜?span lang="EN-US">N.B.Hadjtahar[64]鐮斿埗鎴愬姛澶氬眰閫忔槑瀵肩數纭奸攲锛?span lang="EN-US">BZO锛夎杽鑶溿€?span lang="EN-US">

璁烘枃璇达細“瀹為獙娴嬪緱鐨勯摑閿屾哀鍖栫墿锛?span lang="EN-US">AZO锛夎浇浣撳瘑搴︼紝姣旂〖閿屾哀鍖栫墿锛?span lang="EN-US">BZO锛夌殑澶э紙鍑犱箮涓ゅ€嶏級銆傝繖涓笉鍚屽彲鐢辩數璐熸€у拰闃崇瀛愯矾鏄撳＋閰稿己搴﹀姞浠ュ垎鏋愩€傚紶姘稿拰寤虹珛浜嗛槼绂诲瓙璺槗澹吀寮哄害锛?/span>L_z锛夈€佺數璐熸€э紙X_z锛夊拰绂诲瓙婵€鍖栧姏锛?span lang="EN-US">z/r2锛夌殑鍏崇郴寮?span lang="EN-US">:

L_z = Z/r_k² – 7.7 X_z + 8.0

r_k鏄粡楠岀瀛愬崐寰勶紝Z鏄師瀛愭牳鐢佃嵎鏁般€?span lang="EN-US">Lz, X_z ,鍜?span lang="EN-US">z/r2鐨勬暟鍊艰琛?span lang="EN-US">1銆傜〖鐨?/span>L_z鍜?/span>X_z鍊兼槑鏄剧殑楂橈紝琛ㄦ槑杩欎釜鍘熷瓙涓庢哀鏈夎緝澶х殑閿拰銆傝鏄庢湁杈冨鐨勬哀婊炵暀鍦?span lang="EN-US">BZO钖勮啘涓婏紙鐢氳嚦娣伀鍚庯級銆傝繃澶氱殑姘у師瀛愪腑鍜屼簡鎺哄拰鐗┿€傛彁渚涗簡闄勫姞鐨勪腑鎬ф秷鏁ｄ腑蹇冿紝鍥犺€岄檺鍒朵簡杞戒綋瀵嗗害鍜岃縼绉荤巼銆?span lang="EN-US">……鍥犳锛岄€忔槑瀵肩數浣撻鍩熺殑杩涗竴姝ョ爺绌跺簲璇ラ€氳繃浼樺寲鍚庢矇绉番鐏弬鏁帮紝闆嗕腑浜庡噺灏戜腑鎬у寲鍚堢墿鐨勫瘑搴︺€傚湪杩欐柟闈紝闄嶄綆姘у帇浼氬璐′綋鐨勫啀鐢熸湁鎵€鍔╃泭“銆?span lang="EN-US">

 琛?span lang="EN-US">1. 鍘熷瓙鍙傛暟

[16] Y. Zhang,, Inorg Chem., 1982, 21, 3886.

[17] Y. Zhang,, Inorg Chem., 1982, 21, 3889.

[64] R. B. Hadjtahar and N. B. Hadjtahar, Journal of Materials Science, 2005, 40, 5285.