科学网-叶龙的博客-塑料包装薄膜的阻隔性探究
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瀛﹁€呭彾榫?鍙戣〃浜?010-5-7 11:40:52
锛? 鈹? 娴忚锛?66      

濉戞枡鍖呰钖勮啘鐨勯樆闅旀€ф帰绌?/span>

鍖呰鏉愭枡瀛︽湳璁ㄨ璇剧▼璁烘枃

濉戞枡鍖呰钖勮啘鐨勯樆闅旀€ф帰绌?/span>

鍙堕緳

锛堟姹夊伐绋嬪ぇ瀛︽潗鏂欑瀛︿笌宸ョ▼瀛﹂櫌 06鍖呮潗锛?/font>

銆?/span>鎽樿銆?nbsp;  

       闅忕潃椋熷搧鍜屽尰鑽鍖呰鐨勮姹傝秺鏉ヨ秺涓ユ牸锛屼竴浜涙柊鐨勫姛鑳借杽鑶滀篃鑴遍鑰屽嚭锛屽叾涓珮闃婚殧鎬у鏂欏寘瑁呮潗鏂欏凡鎴愪负濉戞枡鍖呰鏉愭枡鐨勯噸瑕佸彂灞曟柟鍚戜箣涓€锛屾€ц兘浼樺紓鐨勯珮闃婚殧鎬у寘瑁呮潗鏂欏湪椋熷搧鍜屽尰鑽瓑棰嗗煙寰楀埌骞挎硾搴旂敤銆傛湰鏂囩伒娲昏繍鐢ㄧ墿鐞嗗寲瀛﹀拰楂樺垎瀛愮墿鐞嗙殑鍩烘湰鍘熺悊瀵归樆闅旀€х殑鍘熺悊銆佸垎绫汇€佽〃寰併€佹祴璇曞強搴旂敤鐜扮姸鍙婂睍鏈涗綔娣卞叆鐨勯槓杩帮紝骞朵粠鏂囩尞鍏ㄩ潰鎬荤粨鍑烘彁楂樿杽鑶滈樆闅旀€х殑鏂规硶銆?/span>

銆愬叧閿瘝銆?nbsp; 濉戞枡钖勮啘锛涢樆闅旀€э紱娓楅€忕郴鏁帮紱閫忔皵鎬ф祴璇?/span>

The Barrier Properties of Plastic Packaging Films

  Ye  Long

(School of Material Science and Engineering锛學uhan Institute of Technology)

 

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鍥? 娓楅€忚繃绋嬪師鐞嗗浘

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2銆?/span>濉戞枡钖勮啘闃婚殧鎬х殑鍒嗙被

2.1闃绘皵鎬?/span>銆?锝?銆?/span>

     濉戞枡鐨勯樆姘旀€э紝鍗冲鏃犳満姘斾綋锛堟哀姘斻€佹爱姘斻€佷簩姘у寲纰崇瓑锛夌殑閫忚繃鎬э紝鏄互涓嬩袱涓洜绱犵洿鎺ユ湁鍏崇殑锛氳仛鍚堢墿鐨勫嚌缁撹兘width=15鍜岃嚜鐢辩┖闂村瘑搴?/span>width=18銆傚嚌缁撹兘琛ㄧず鑱氬悎鐗╅摼鐨勬椿鍔ㄥ姏锛岃仛鍚堢墿閾鹃棿鐨勭粨鍚堝姏瓒婂己锛孫2銆丆O2绛夋皵浣撶敱浜庡帇鍔涘樊鑰屼镜鍏ラ€氳繃鑱氬悎鐗╅摼闂寸殑鍙兘鎬ц秺灏忥紝闃婚殧鎬у氨瓒婂ソ銆傝嚜鐢辩┖闂存槸琛ㄧず鑱氬悎鐗╅摼浠ヨ嚜鐢辩殑鐘舵€佸崰鎹殑浣撶Н锛岃嚜鐢辩┖闂村瘑搴﹁秺澶э紝鑱氬悎鐗╅摼闂寸殑绌洪棿瓒婂ぇ锛屾皵浣撻€忚繃瓒婂鏄撱€傚皢涓婅堪鍥犵礌缁煎悎鑰冭檻鍙互鐢ㄩ€忚繃鐑?/span>width=15鎻忚堪锛?/span>width=138銆傞樆姘旀€у叿浣撳奖鍝嶅洜绱犺〃鐜颁负锛?/span>鈶?/span>鍒嗗瓙閾剧殑鏋佹€э紱鈶?/span>鍒嗗瓙閾剧殑鍒氭€э紱鈶?/span>缁撴櫠搴︼紱鈶?/span>楂樿仛鐗╃殑瀵嗗害锛?/span>鈶?/span>鍙栧悜搴︼紱鈶?/span>婀挎晱搴︼紱鈶?/span>娓╁害銆?/span>

2.2闃绘箍鎬?/span>銆?锛?銆?/span>

闃绘箍鎬э紝涔熷嵆閫忔箍鎬э紝鎸囩殑鏄杽鑶滃姘磋捀姘旂殑閫忚繃鎬с€傛按钂告皵閫忚繃楂樿仛鐗╁寘瑁呮潗鏂欑殑鏈虹悊锛屽熀鏈笂涓庢棤鏈烘皵浣撻€氳繃鐨勬満鐞嗙浉鍚岋紝涓嶅悓涔嬪鍦ㄤ簬姘磋捀姘旀槸鏋佹€у垎瀛愶紝鏃犳満姘斾綋鏄潪鏋佹€у垎瀛愩€傜敱姝よ€屽甫鏉ヤ竴涓嬪樊鍒€?/span>

鈶?/span>姘磋捀姘斿浜叉按鎬ч珮鑱氱墿鐨勬笚閫忔€э細瀵圭氦缁寸礌钖勮啘銆丳VA銆丒VOH銆丳A绛夊惛姘存€ч珮鑱氱墿銆傛按钂告皵瀵硅杽鑶滅殑鎵╂暎绯绘暟闅忔按钂告皵娴撳害鐨勫澶ц€屽鍔犮€傝€屽闈炰翰姘存€х殑楂樿仛鐗╋紝鎵╂暎绯绘暟鏄笉鍙樼殑銆?/span>

鈶?/span>姘磋捀姘斿鏋佹€у垎瀛愯杽鑶滅殑娓楅€忥細姘磋捀姘旀槸鏋佹€у垎瀛愶紝瀵规瀬鎬ч珮鑱氱墿鐨勬憾瑙i€熺巼鍜屾墿鏁i€熺巼鍧囧ぇ浜庨潪鏋佹€у垎瀛愬鏂欍€?/span>

鈶?/span>姘磋捀姘旂殑娓楅€忔€т笌鍒嗗瓙鑱氶泦鎬佺粨鏋勬湁鍏筹細 鏅舵€侀珮鑱氱墿鐨勭殑娓楅€忛€熺巼澶т簬闈炴櫠鎬侀珮鑱氱墿锛涘瘑搴︿綆鐨勬笚閫忚兘鍔涘ぇ浜庡瘑搴﹂珮鐨勮仛鍚堢墿锛涙棤鍙栧悜鎺掑垪鐨勯珮鑱氱墿娓楅€忔€уぇ浜庡彇鍚戞帓鍒楃殑楂樿仛鐗┿€?/span>

2.3鏈夋満鐗╂笚閫忔€э紙闃绘补鎬э級銆?銆?/span>

涓€鑸寰嬫槸闃绘哀姘旀€уソ鐨勬潗鏂欙紝瀵规湁鏈虹墿鍜屾皵鍛崇殑闃婚殧鎬уソ锛屽姘村垎鏁忔劅鐨勯珮鑱氱墿锛屾湁鏈虹墿娓楅€忔€т竴鑸篃杈冮珮銆傛湁鏈虹墿娓楅€忎笌浠ヤ笅鍥犵礌鏈夊叧锛?/span>鈶?/span>鏋佹€э細鏋佹€х浉杩戠殑鏈夋満鐗╁鐩稿簲鐨勯珮鑱氱墿娓楅€忔€уぇ锛?/span>鈶?/span>鍒嗗瓙閲忥細鏈夋満鐗╁垎瀛愰噺澶х殑閫忚繃鎬у樊锛?/span>鈶?/span>婧惰В搴﹀弬鏁帮細鏈夋満鐗╀笌楂樿仛鐗╃殑婧惰В搴﹀弬鏁扮浉杩戠殑鏄撴笚閫忋€?/span>

2.4淇濋鎬?/span>銆?銆?/span>

   淇濋鎬ф槸鏉愭枡闃婚殧鎬у洜绱犵殑缁煎悎浣撶幇锛屽寘鎷簡娓楅€忋€佹湁鏈虹墿娓楀嚭銆佽縼绉汇€佽浆绉荤瓑鏈虹悊銆傚奖鍝嶄繚棣欐€х殑鍥犵礌鏈夛細鈶燨2銆丠2O鐨勬笚閫忓紩璧烽鍛冲彉鍖栵紱鈶℃湁鏈虹墿灏忓垎瀛愭笚閫忓紩璧烽鍛冲彉鍖栵紱鈶㈤珮鑱氱墿鍖呰鏉愭枡涓垚鍒嗙殑杩佺Щ寮曡捣寮傚懗锛涒懀鍖呰鍐呭鐗╅鍛虫垚鍒嗙殑杞Щ鍜屾暎澶憋紝瀵艰嚧棣欏懗鎴愬垎鐨勫噺灏戙€?/span>瀹為獙琛ㄦ槑鍖呰鏉愭枡鐨勯樆闅旀€ц秺濂斤紝淇濋鎬т篃瓒婂ソ銆?/span>

3銆?/span>濉戞枡钖勮啘闃婚殧鎬х殑琛ㄥ緛銆?锛?銆?/span>

     琛ㄥ緛楂樺垎瀛愭潗鏂欓樆闅旀€э紙閫忚繃鎬э級澶у皬鐨勬寚鏍囦负閫忚繃绯绘暟锛屽寘鎷皵浣撻€忚繃绯绘暟銆佹按钂告皵閫忚繃绯绘暟锛岄€氬父鏄寚鍦ㄦ亽瀹氭俯搴﹀拰鐩稿婀垮害鐜涓紝鍦ㄧǔ瀹氶€忚繃鏃讹紝鍗曚綅鏃堕棶鍐呴€忚繃璇曟牱鍗曚綅鍘氬害銆佸崟浣嶉潰绉唴閫忚繃灏忓垎瀛愮墿璐ㄧ殑浣撶Н鎴栭噸閲忋€?/span>

3.1 娓楅€忕郴鏁癙

width=158锛?锛?/span>

    寮忎腑width=15涓哄鍚堢粨鏋勬€诲帤搴︼紱width=96涓烘瘡灞傝啘鐨勫帤搴︼紱width=942涓烘瘡灞傝啘鐨勬笚閫忕郴鏁般€備粠璇ュ叕寮忓彲浠ョ湅鍑猴紝闃婚殧鎬т富瑕佸彇鍐充簬闃婚殧鎬ф渶濂界殑涓€灞傜殑闃婚殧鎬э紝澶嶅悎鑶滅殑鍏朵粬閮ㄥ垎瀵归樆闅旀€у彧鏄捣浜嗚浇浣撲綔鐢ㄣ€傞殢鐫€楂樿仛鐗╂潗鏂欏湪鍖呰甯傚満涓簲鐢ㄩ鍩熷強闇€姹傞噺鐨勫姞澶э紝鏂板瀷鍔熻兘鏉愭枡寮€鍙戣繘搴︿笉鏂姞蹇紝闃婚殧鎬ц杽鑶滅爺鍙戞祴璇曞凡涓嶅啀灞€闄愪簬娓楅€忕郴鏁般€佹笚閫忛噺绛夋寚鏍囦笂锛屽鎵╂暎绯绘暟銆佹憾瑙e害绯绘暟绛夌洿鎺ュ奖鍝嶅悜娓楅€忓弬鏁扮殑娴嬭瘯闇€姹傞€愭笎澧炲锛屾潗鏂欑殑闃婚殧娴嬭瘯宸叉鍏ラ€愭笎瀹屽杽鐨勮繃绋嬨€?/span>

3.2 姘斾綋閫忚繃鐜囩郴鏁癙g

width=160锛?锛?/span>

    寮忎腑Qg-姘斾綋閫忚繃閲?锛汥-璇曟牱鍘氬害

3.3 姘磋捀姘旈€忚繃鐜囩郴鏁癙v

width=210锛?锛?/span>

   寮忎腑WVT-姘磋捀姘旈€忚繃绯绘暟锛汥-璇曟牱鍘氬害锛?/span>鈻?/span>P-璇曟牱涓や晶鐨勬按钂告皵鍘嬪樊

琛?  甯歌闃婚殧鎬ф潗鏂欑殑閫忚繃绯绘暟

锛堝崟浣嶏細width=276锛?/span>

閫忚繃绯绘暟

楂樿仛鐗?/span>

姘ф皵

浜屾哀鍖栫⒊

姘?/span>

EVOH锛堜箼鐑?9%锛?/span>

0.1

0.5

20-25

EVOH锛堜箼鐑?8%锛?/span>

0.4

6

40-70

PVDC鍏辫仛鐗?/span>

0.5-4

1.2

0.2-6

PAN鍏辫仛鐗?/span>

8

16

50

PEN

12-22

50

5-9

PA-66

15-30

50-70

-

PA-6

25-40

150-200

150

PET

49-90

180

18-30

4銆?/span>濉戞枡钖勮啘闃婚殧鎬х殑妫€娴?/span>

    鍦ㄩ€夋嫨鍖呰鏉愭枡骞惰繘琛屾潗鏂欑殑缁撴瀯璁捐鏃讹紝濡備綍妫€娴嬫潗鏂欑殑闃婚殧鎬ф寚鏍囷紝鏄褰撳叾鍐查渶瑕佽В鍐崇殑闂銆傝瘯楠屾柟娉曠殑閫夋嫨浠ュ強鏁版嵁涔嬮棿鏄惁鍏锋湁鍙瘮鎬ч兘鏄叧娉ㄧ殑鐒︾偣銆傜敱浜庢潗鏂欏姘ф皵浠ュ強姘磋捀姘旈樆闅旀€х殑妫€娴嬮渶姹傛渶寮猴紝鍥犳妫€娴嬪彂灞曞緢蹇€傚父鐢ㄧ殑姘ф皵閫忚繃鎬ф娴嬫柟娉曟湁锛氬帇宸硶锛堢湡绌烘硶鍜屽父鍘嬫硶锛夈€佺瓑鍘嬫硶锛堟哀浼犳劅鍣ㄦ硶锛夛紱姘磋捀姘旈樆闅旀€ф娴嬫柟娉曟湁锛氱О閲嶆硶銆佷紶鎰熷櫒娉曪紙婀垮害浼犳劅鍣ㄦ硶銆佺孩澶栨帰娴嬪櫒娉曘€佺數瑙f硶锛夛紝濡傚浘2鎵€绀恒€?/span>銆?锛?锛?銆?/span>闃婚殧鎬ф娴嬭澶囬兘鏄珮绔簿瀵嗕华鍣紝鑰屼笖娴嬭瘯鍏锋湁寰堝己鐨勭幆澧冧緷璧栨€э紝鏃犺缁存姢鍜屼娇鐢紝閮芥槸涓€鑸殑鏉愭枡鐗╃悊鎬ц兘妫€娴嬭澶囨墍涓嶈兘鐩告瘮鐨勩€?/span>

鍥?  闃婚殧鎬х殑娴嬭瘯鏂规硶

width=525

4.1閫忔皵鎬ф祴璇?/span>銆?锛?1锛?4銆?/span>

    閫忔皵鎬ф祴璇曪紝涔熺О姘斾綋闃婚殧鎬ф祴璇曪紝涓昏鏄€冨療钖勮啘瀵瑰父瑙佹棤鏈烘皵浣撶殑闃婚殧鎬ц兘,鏄杽鑶滀富瑕佺殑闃婚殧鎬ф寚鏍囦箣涓€銆傞€氬父妫€娴嬬殑鏄鏂欒杽鑶滄潗鏂欑殑閫忔哀鎬э紝鐢变簬姘旇皟鍖呰锛?/span>Modified Atmosphere Packaging锛?/span>鐨勫箍娉涘簲鐢紝涔熼渶瀵瑰寘瑁呮潗鏂欑殑浜屾哀鍖栫⒊銆佹爱姘旈€忚繃鎬ц繘琛屾娴嬨€傝繖閲屼富瑕佷粙缁嶅帇宸硶涓庣瓑鍘嬫硶銆?/span>

4.1.1鍘嬪樊娉曪紙Differential-pressure method锛?/span>

绗﹀悎鍘嬪樊娉曞師鐞嗙殑鐢ㄤ簬妫€娴嬫哀姘旈€忚繃閲忕殑妫€娴嬩华鍣ㄦ湁鍥藉唴娴庡崡鍏板厜鏈虹數鎶€鏈湁闄愬叕鍙哥敓浜х殑VAC绯诲垪鍘嬪樊娉曟皵浣撴笚閫忎华锛屽叾鏈€楂樼簿搴﹀彲杈?.01cm3/m2•24h•0.1MPa銆傜湡绌烘硶鏄帇宸硶涓渶鍏蜂唬琛ㄦ€х殑涓€绉嶆祴璇曟柟娉曪紝涔熸槸姘斾綋娓楅€忓畾涔夌殑鏂规硶銆傚叾娴嬭瘯鍘熺悊锛堝鍥?鎵€绀猴級鏄埄鐢ㄨ瘯鏍峰皢娓楅€忚厰闅旀垚涓や釜鐙珛鐨勭┖闂达紝鍏堝皢璇曟牱涓や晶閮芥娊鎴愮湡绌猴紝鐒跺悗鍚戝叾涓竴渚у厖鍏?.1MPa锛堢粷鍘嬶級鐨勬祴璇曟皵浣擄紝鑰屽彟涓€渚у垯淇濇寔鐪熺┖鐘舵€併€傝繖鏍峰湪璇曟牱涓や晶灏卞舰鎴愪簡0.1MPa鐨勬祴璇曟皵浣撳帇宸紝娴嬭瘯姘斾綋娓楅€忛€氳繃钖勮啘杩涘叆浣庡帇渚у苟寮曡捣浣庡帇渚у帇鍔涚殑鍙樺寲銆傞€氳繃浣跨敤楂樼簿搴︽祴鍘嬭娴嬮噺浣庡帇渚х殑鍘嬪姏鍙樺寲閲忓氨鍙互鍒╃敤鍏紡璁$畻寰楀埌姘斾綋閫忚繃閲忋€?/span>

鍘嬪樊娉曞叿鏈夊娴嬭瘯姘斾綋娌℃湁閫夋嫨鎬с€佹祴璇曟垚鏈綆銆佽瘯楠屾垚鍔熺巼楂樼瓑鏄捐憲鐨勬娴嬩紭鍔匡紝鐒惰€屾渶涓虹獊鍑虹殑褰撴暟鍦ㄥ叾娴嬭瘯鐜涓皵浣?ldquo;绾噣”銆傚洜涓哄湪鐪熺┖娉曠殑璇曢獙杩囩▼涓細鍏堝鏁翠釜娴嬭瘯鑵旀娊鐪熺┖鑷?7Pa浠ヤ笅锛屽啀瀵规祴璇曚笂鑵斿厖鍏ョ函鍑€鐨勬祴璇曟皵浣擄紝杩欐牱鍦ㄦ暣涓瘯楠岀幆澧冧腑鐨勬潅璐ㄦ皵浣擄紙闈炶瘯楠屾皵浣擄級灏卞彲浠ュ拷鐣ヤ簡锛屽洜姝ゆ潅璐ㄦ皵浣撳彲鑳界粰璇曢獙甯︽潵鐨勫奖鍝嶅氨鑳芥帓闄や簡銆?/span>銆?4銆?/span>

width=340

鍥? 鍘嬪樊娉曡瘯楠屽師鐞嗗浘

4.1.2绛夊帇娉曪紙Equal-pressure method锛?/span>

鐩墠搴旂敤浜庨€忔皵鎬ф娴嬬殑绛夊帇娉曚富瑕佹槸浼犳劅鍣ㄦ硶锛屽畠涓昏鐢ㄤ簬姘ф皵閫忚繃鎬ф娴嬶紝娴嬭瘯鍘熺悊濡傚浘4鎵€绀猴細鍒╃敤璇曟牱灏嗘笚閫忚厰闅旀垚涓や釜鐙珛鐨勬皵娴佺郴缁燂紝涓€渚т负娴佸姩鐨勬祴璇曟皵浣擄紙鍙互鏄函姘ф皵鎴栨槸鍚哀姘旂殑娣峰悎姘斾綋锛夛紝鍙︿竴渚т负娴佸姩鐨勫共鐕ヨ浇姘旓紙姘皵锛夈€傝瘯鏍蜂袱杈圭殑鍘嬪姏鐩哥瓑锛屼絾姘ф皵鍒嗗帇涓嶅悓銆傚湪姘ф皵鐨勫垎鍘嬪樊浣滅敤涓嬶紝姘ф皵閫忚繃钖勮啘骞惰姘皵娴侀€佽嚦浼犳劅鍣ㄤ腑锛岀敱浼犳劅鍣ㄧ簿纭祴閲忓嚭姘皵娴佷腑鎼哄甫鐨勬哀姘旈噺锛屼粠鑰岃绠楀嚭鏉愭枡鐨勬哀姘旈€忚繃鐜囥€?/span>

绛夊帇娉曠殑绐佸嚭浼樼偣鏄彲浠ヨ繘琛屽鍣ㄩ€忔哀鎬ф娴嬶紝浣嗗湪娴嬭瘯姘斾綋鐨勯€氱敤鎬т笂涓嶅鍘嬪樊娉曞箍娉涖€傜敱浜庡湪绛夊帇娉曟祴璇曞師鐞嗕腑瀵硅浇姘旂殑闇€瑕佷娇寰楀湪璇ユ柟娉曚腑瀛樺湪涓ょ鏁伴噺鐩稿綋鐨勬皵浣擄紝褰撹瘯鏍蜂袱渚ф湁0.1MPa姘ф皵鍒嗗帇宸瓨鍦ㄧ殑鍚屾椂涔熸湁0.1MPa姘皵鍒嗗帇宸瓨鍦紝涓嶈繃瀹冧滑鐨勬搴︽柟鍚戞濂界浉鍙嶏紝鍥犳鍦ㄧ瓑鍘嬫硶涓綋姘ф皵娓楅€忛€氳繃钖勮啘鐨勫悓鏃舵爱姘旇繘琛岀潃閫嗗悜鐨勬笚閫忋€?/span>

width=475

鍥? 绛夊帇娉曡瘯楠屽師鐞?/span>

4.2閫忔箍鎬ф祴璇?/span>銆?2锛?3銆?/span>

鏉紡娉曪紝鍙堝彨绉伴噸娉曪紙weighing method锛夛紝鏄洰鍓嶆垜鍥藉浗瀹舵爣鍑嗗敮涓€璁ゅ彲鐨勯€忔箍鎬ф祴璇曟柟娉曘€傛垜鍥界殑璐ㄦ绯荤粺浠ュ強閫愭笎鍙戝睍璧锋潵鐨勪腑鍥藉寘瑁呭伐涓氳嚜涓婁笘绾?O骞翠唬璧峰湪杩涜鏉愭枡鐨勯€忔箍鎬ф娴嬫椂灏卞叏閮ㄩ噰鐢ㄦ澂寮忔硶銆傛澂寮忔硶鍙互鍒嗕负娓楅€忚繘鍏ラ€忔箍鏉殑澧為噸娉曞拰娓楅€忕寮€閫忔箍鏉殑鍑忛噸娉曚袱绉嶆祴璇曟柟娉曘€傚閲嶆硶鐨勯€忔箍鏉腑鏀炬湁骞茬嚗鍓傦紝鍙涓洪€忔箍鏉唴閮ㄤ负0锛匯H锛岃瘯楠岀幆澧冧负38鈩?nbsp;銆?0锛匯H锛涜€屽湪鍑忛噸娉曚腑閫忔箍鏉唴鐩涙湁钂搁姘存垨鏄ケ鍜岀洂婧舵恫锛屽鏋滅洓鐨勬槸钂搁姘村彲璁や负閫忔箍鏉唴閮ㄤ负100锛匯H锛岃瘯楠岀幆澧冧负38鈩?nbsp;銆?O锛匯H銆?/span>

5銆?/span>甯歌楂橀樆闅旇杽鑶滄潗鏂欑殑闃婚殧鎬у垎鏋?/span>銆?锛?锛?锛?锛?5锝?9銆?/span>

    钖勮啘闃婚殧鎬ц兘鏄寚瀵瑰皬鍒嗗瓙姘斾綋濡傛哀銆佹按姹姐€佹恫浣撳強姘斿懗绛夌殑灞忚斀鑳藉姏锛岄樆闅旀€ц杽鑶滀富瑕佺敤浜庨鍝佸拰鍖昏嵂鍖呰锛岀‘淇濆寘瑁呯墿鍦ㄥ偍瀛樸€佽繍杈撹繃绋嬩腑淇濋淇濆懗涓嶅彉璐紝浠ュ欢闀垮叾淇濊川鏈熷拰璐ф灦瀵垮懡銆傞殢鐫€鐢熸椿鑺傚鐨勫姞蹇拰鐢熸椿姘村钩鐨勬彁楂?nbsp;鍚勭鏂逛究椋熷搧濡傝倝鍒跺搧銆佷钩鍒跺搧銆佹饭鍗ゅ埗鍝佺瓑鐨勯渶姹傞噺瓒婃潵瓒婂ぇ锛屽鍖昏嵂浜у搧鐨勮川閲忚姹備篃瓒婃潵瓒婇珮锛屾澶栭樆闅旀€у鏂欒杽鑶滀篃骞挎硾搴旂敤鍦ㄥ寲濡嗗搧銆佽尪鍙躲€佸寲瀛﹁瘯鍓傘€佸啘鑽€侀鏂欍€侀ゲ鏂欑瓑浜у搧鐨勫寘瑁咃紝鍥犳闃婚殧鎬ц杽鑶滃凡鎴愪负鍚勫浗绔炵浉寮€鍙戠殑鐑偣銆?/span>

     鍦ㄩ樆闅旀€у鏂欒杽鑶滀腑闃婚殧鎬ф爲鑴傜殑浣跨敤鏄叧閿紝涓昏鏈夎仛涔欑儻閱?PVA)銆佷箼鐑箼鐑唶鍏辫仛鐗?EVOH)銆佸亸姘箼鐑叡鑱氱墿(PVDC)銆佽仛钀樹簩鐢查吀涔欎簩閱囬叝(PEN)銆佺壒娈婂凹榫?MXD6)銆佸凹榫?PA)銆佽仛瀵硅嫰浜岀敳閰镐箼浜岄唶(PET)绛夛紝鍦ㄨ繖浜涢樆闅旀€ф爲鑴備腑锛孭VA銆丒VOH銆丳VDC銆丳EN灞炰簬楂橀樆闅旀€ф潗鏂欙紝鏈€甯哥敤鐨勬槸PVDC鍜孍VOH锛岃€孭A涓嶱ET鐨勯樆闅旀€х浉杩戯紝灞炰簬涓樆闅旀€ф潗鏂欍€?/span>銆?5銆?/span>

5.1 PVDC锛堣仛鍋忎簩姘箼鐑?/span>锛?/span>Polyvinylidene Chloride锛?/span>
銆€銆€PVDC鏄綋浠婁笘鐣屼笂缁煎悎闃婚殧鎬ф渶濂界殑楂樺垎瀛愭潗鏂欙紝涔?/span>鏄渶鏃╁紑鍙戠殑楂橀樆闅旀€ф潗鏂欙紝浣跨敤鍘嗗彶杈冮暱锛屼粠8O骞翠唬寮€濮嬪箍娉涚敤浜庨鍝佸寘瑁咃紝鍥藉唴涓昏鐢ㄤ綔鑲犺。鑶滐紝PVDC鍏锋湁鏋佸ソ鐨勯樆姘ч樆婀挎€ц兘锛?nbsp;浣嗘槸鐢变簬鍚隘鑰屽彈鍒扮幆淇濅汉鍦熺殑鍙嶅锛屽湪娆ф床鐨勪竴浜涘浗瀹跺睘绂佺敤鏉愭枡銆?/span>
    PVDC娑傝钖勮啘浣跨敤閲忕壒鍒锛?/span>鐢变簬绾殑PVDC杞寲娓╁害楂橈紝涓斾笌鍏跺垎瑙f俯搴︽帴杩戯紝鍙堜笌涓€鑸濉戝墏鐩告憾鎬у樊锛屾晠鍔犵儹鎴愬瀷鍥伴毦鑰屼笖闅句互鐩存帴搴旂敤銆傚疄闄呬娇鐢ㄧ殑PVDC钖勮啘澶氫负鍋忔隘涔欑儻(VDC)鍜屾隘涔欑儻(VC)鐨勫叡鑱氱墿銆?/span>
銆€銆€PVDC鐨勭壒鐐规槸浣庨€忚繃鎬с€侀樆闅旀€у拰鑰愬寲瀛﹁嵂鍝佹€с€傛垜鍥絇VDC鏄即闅忕潃鐏吙鑲犲姞宸ユ妧鏈紩杩涘苟寰楀埌鍙戝睍鐨勩€傜洰鍓嶅凡骞挎硾搴旂敤浜庨鍝併€佸嵎鐑熴€侀ギ鏂欎繚椴滃拰闅斿懗锛屼互鍙婂寲宸ャ€佸尰鑽€佺數瀛愬拰鍐涘伐浜т笟鐨勯槻娼寘瑁?/span>銆?/span>

5.2 EVOH锛堜箼鐑?/span>涔欑儻閱囧叡鑱氱墿锛?/span>Ethylene - vinyl alcohol copolymer锛?/span>
銆€銆€EVOH涓€鐩存槸搴旂敤鏈€澶氱殑楂橀樆闅旀€ф潗鏂欍€?/span>EVOH鐨勯樆闅旀€ц兘鍙栧喅浜庝箼鐑殑鍚噺锛屼竴鑸潵璇?/span>锛?/span>褰撲箼鐑惈閲忓鍔犳椂鍊欙紝姘斾綋闃婚殧鎬т笅闄嶏紝浣嗘槗浜庡姞宸ャ€侲VOH鏄捐憲鐗圭偣鏄姘斾綋鍏锋湁鏋佸ソ鐨勯樆闅旀€у拰鏋佸ソ鍔犲伐鎬э紝鍙﹀閫忔槑鎬с€佸厜娉芥€с€佹満姊板己搴︺€佷几缂╂€с€佽€愮(鎬с€佽€愬瘨鎬у拰琛ㄩ潰寮哄害閮介潪甯镐紭寮傘€?/span>

EVOH缁撴瀯涓瓨鍦ㄧ緹鍩猴紝EVOH鍏锋湁浜叉按鎬у拰鍚告箍鎬э紝鏁?/span>EVOH甯镐綔澶嶅悎鑶滀腑闂撮樆闅斿眰锛屽簲鐢ㄥ湪鎵€鏈夌殑纭€у拰杞€у寘瑁呬腑锛涘湪椋熷搧涓氫腑鐢ㄤ簬鏃犺弻鍖呰銆佺儹缃愬拰钂哥叜琚嬶紝鍖呰濂跺埗鍝併€佽倝绫汇€佹灉姹佺綈澶村拰璋冨懗鍝侊紱鍦ㄩ潪椋熷搧鏂归潰锛岀敤浜庡寘瑁呮憾鍓傘€佸寲瀛﹁嵂鍝佺瓑銆傚湪椋熷搧鍖呰鏂归潰锛孍VOH鐨勫鏂欏鍣ㄥ畬鍏ㄥ彲浠ユ浛浠g幓鐠冨拰閲戝睘瀹瑰櫒锛屽浗鍐呭瀹舵按浜у叕鍙稿嚭鍙f捣椴滃氨浣?/span>鐢?/span>PE/EVOH/PA/EVOH/PE浜斿眰鍏辨尋鍑鸿啘鐪熺┖鍖呰銆?/span>
5.3 灏奸緳绫伙紙Nylon锛?/span>

灏奸緳绫诲寘瑁呮潗鏂欎互鍓嶄竴鐩翠娇鐢ㄥ凹榫?/span>-6銆備絾鏄凹榫?/span>-6鐨勬皵瀵嗘€т笉鐞嗘兂銆?/span>閰拌兒鍩烘槗褰㈡垚姘㈤敭杩戝勾鏉ユ棩鏈柊寮€鍙戝嚭鏉ョ殑涓€绉?/span>鏂板瀷鏉愭枡——鐗规畩灏奸緳(MXD6)锛屽叾姘斿瘑鎬ф瘮“灏奸緳6”楂?0鍊嶄箣澶?/span>锛?/span>瀹冩槸鐢遍棿鑻簩鐢茶兒鍜屽繁浜岄吀鐨勭缉鑱氫骇鐗╋紝涓哄崐缁撴櫠鑱氬悎鐗?/span>锛?/span>鍏锋湁鍑鸿壊鐨勯樆閫忔€э紝涓斿叾闃婚€忔€т笉闅忔箍搴︾殑澧炲姞鑰屼笅闄?/span>銆備富瑕佺敤浜庨珮闃婚€忔€ц杽鑶滃拰楂樺己搴﹂樆闅旀€ф潗鏂欙紝鍙﹀杩樺彲鐩存帴鐢ㄤ簬椋熷搧鍖呰棰嗗煙锛岀敤浜庨渶瑕佽捀鐓姞宸ョ殑椋熷搧鍖呰銆?/span>鍦ㄦ娲诧紝鐢变簬鐜淇濇姢闂绐佸嚭锛屼綔涓篜VDC绫昏杽鑶滅殑鏇夸唬浜у搧锛孧XD6灏奸緳銆?6銆?/span>鐨勪娇鐢ㄩ噺鏄緢澶х殑銆?/span>杩戝勾鏉ラ殢鐫€绾崇背鎶€鏈殑鏂拌捣锛岃仛閰拌兒绾崇背鎶€鏈鍚堟潗鏂欑殑鐮旂┒鏋佷负娲昏穬锛屽浗鍐呭宸叉垚鍔熷紑鍙戜簡寰堝鑱氶叞鑳虹撼绫冲鍚堟潗鏂?/span>銆?/span>

5.4 PET锛堣仛瀵硅嫰浜岀敳閰镐箼浜岄唶閰紝Polyethylene terephthalate锛?/span>

PET鏈夎緝濂界殑姘斾綋(姘ф皵銆佷簩姘у寲纰冲強姘存苯)闃婚殧鎬?灞炰簬涓瓑闃婚殧鏉愭枡锛?/span>閫氳繃閫傚綋鐨勬敼鎬ф柟娉曪紝濡傚叡娣枫€佸鍚堛€佸~鍏呯瓑鏂规硶閮藉彲涓嶅悓绋嬪害鍦版彁楂樺叾闃婚殧鎬ц兘銆傚叿鏈夐樆闅旀€х殑楂樺垎瀛愭潗鏂欏湪搴旂敤涓湁涓ゅぇ浼樺娍锛氫竴鏄兘鏈夋晥鐨勯槻姝㈢┖姘斾腑鐨勬哀姘旈€氳繃瀹瑰櫒鐨勫櫒澹佽繘鍏ュ埌瀹瑰櫒涓紝鑳芥湁鏁堢殑淇濇姢濉戞枡瀹瑰櫒鎵€鍖呰鐨勯鍝佽嵂鍝佺瓑澶氱鍟嗗搧锛岄伩鍏嶅畠浠洜鍙楁哀姘旂殑浣滅敤鑰屽紩璧峰彉鍧€锛屼粠鑰屽欢闀垮晢鍝佺殑淇濊川鏈熷強璐ф灦鏈?/span>锛?/span>鍏朵簩鏄槻姝㈠鍣ㄤ腑鎵€鍖呰鐨勯潪鏋佹€ф憾鍓傜瓑鍟嗗搧閫氳繃瀹瑰櫒鍣ㄥ鑰屾暎閫革紝鍑忓皯鍟嗗搧鍌ㄥ瓨杩囩▼涓殑鎹熷け骞舵敼鍠勭幆澧冭川閲忋€?/span>

5.5 PVA锛堣仛涔欑儻閱囷紝polyvinyl alcohol锛?/span>

PVA闃绘皵鎬у崄鍒嗕紭鑹紝鏄鏂欎腑闃绘皵鏈€濂界殑銆傞唶钂告苯涔熼毦浠ユ笚閫忥紝鏇翠笉鏄撻€忚繃绌烘皵锛屼絾鏄敱浜庡惈鏈夊ぇ閲忕殑缇熷熀锛屽惛姘存€у己锛屾箍寮哄害浣庯紝涓旈樆姘旀€ч殢鍚告箍閲忕殑澧炲ぇ鑰屾湁鎵€涓嬮檷锛屾妸涔欑儻閱囦笌涔欑儻鍏辫仛寰楀埌鐨凟VOH(涓€鑸箼鐑惈閲忎负25锛咃綖45锛?鍑忓皯浜嗘潗鏂欎腑鐨勭緹鍩猴紝浠庤€屽叾闃绘箍鎬ц兘澶уぇ鏀瑰杽锛屽敖绠¢樆姘ф€ф湁鎵€涓嬮檷锛屼絾浠嶇劧鏄瘮PVDC浼樿壇鐨勯珮闃婚殧鎬ф潗鏂欙紝鍥犳PVA涓嶦VOH鐨勭己鐐瑰湪浜庢潗鏂欎腑鐨勭緹鍩烘槗涓庣幆澧冧腑鐨勬按缁撳悎鎴愭阿閿紝鍏堕樆婀挎€ц兘鍙楁箍搴﹀奖鍝嶈緝澶э紝鏁呭彧鑳界敤浜庡唴灞傘€?/span>

6銆侀樆闅旀€х爺绌剁幇鐘跺強灞曟湜銆?7锝?6銆?/span>

浜屽崄涓栫邯涔濆崄骞翠唬鍒濆熀鏈笂鏈?绉嶉樆闅斿寘瑁呰杽鑶滐細灏奸緳銆丳VDC锛堣仛鍋忎簩姘箼鐑級銆丒VOH 锛堜箼鐑唶鍏辫仛鏍戣剛锛夊拰閲戝睘鍖栧鍚堣杽鑶溿€備絾鏄秷璐硅€呰姹傛洿鍔犳柊椴滃懗缇庛€佽川閲忔洿浼樼殑椋熷搧锛岃繖淇冭繘鍖呰涓氱爺绌跺嚭鏇村厛杩涚殑鍖呰鏂规銆備粖澶╋紝浜轰滑鍙互浜彈澶氳揪15灞傜殑澶嶅悎钖勮啘銆傚浗澶栫殑涓撳鎶婇珮闃婚殧鎬ц蒋鍖呰鏉愭枡瀹氫箟涓?ldquo;浠讳綍鑳藉闃绘鍙︿竴绉嶇墿璐紙涓嶇鏄皵浣撴垨棣欏懗锛変镜鍏ョ殑鏉愭枡”銆備粖澶╂墍浣跨敤鐨勯珮闃婚殧鎬ф潗鏂欓€氬父灞炰簬闃绘哀鏉愭枡锛屽叾涓渶甯哥敤鐨勬湁EVOH鍜屽凹榫欐爲鑴傦紝瀹冧滑鍚岃仛涔欑儻涓€璧蜂娇鐢紙鑱氫箼鐑湪杩欓噷璧烽樆姘存垨闃叉疆浣滅敤锛夈€侾P鍜孭ET缁忓父鐢ㄤ綔楂橀樆闅旀€у鍚堣杽鑶滅殑鍩鸿啘銆備粖澶╋紝浼樿川闃婚殧鎬ц杽鑶滄垨楂橀樆闅旀€ц蒋鍖呰绐佸嚭鍦板簲鐢ㄥ湪闆跺敭椋熷搧甯傚満銆?/span>

鍦ㄦ柊鏉愭枡鐨勫紑鍙戞柟闈紝缇庡浗銆佹棩鏈瓑鍥藉鐨勪笓涓氱敓浜т紒涓氬仛浜嗗ぇ閲忕殑宸ヤ綔锛岄€氳繃鏀规€ф妧鏈紝鍚勭鍏锋湁鏂板姛鑳界壒鎬х殑鏂扮墝鍙锋爲鑴備笉鏂帹鍑猴紝濡傚惞濉戠骇PVA鍜孭VDC銆佸彲鎷変几鐨凟VOH銆侀樆闅旀€ц寕閲戝睘鑱氫笝鐑瓑锛屽洜姝ゅ湪鍘熸枡鐨勪娇鐢ㄦ柟闈紝鍥藉唴浼佷笟鍏锋湁鏇村鐨勯€夋嫨闈€?/span>銆?4銆?/span>

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闃婚殧鎬ч珮鍒嗗瓙钖勮啘鏉愭枡杩囧幓闆嗕腑鍦ㄩ樆闅斿眰鐨勫埗澶囦笌鍔犲叆,鏉愭枡澶氬眰澶嶅悎涓庤〃闈㈢殑澶勭悊銆傛潗鏂欓樆闅旀€т笌鏉愭枡缁撴瀯涔嬮棿鍏崇郴鐮旂┒,鏉愭枡鍔犲伐宸ヨ壓涓庢潗鏂欏嚌鑱氭€佺粨鏋勩€侀樆閫忔€т箣闂村叧绯荤殑鐮旂┒鏄毦鐐逛篃鏄噸鐐广€傜矘鍦熶笌楂樺垎瀛愭潗鏂欏鍚?鍒跺鏂板瀷闃婚殧鎬ф潗鏂欌攢绾崇背澶嶅悎闃婚殧鎬ф潗鏂欐槸鏈潵绾崇背鎶€鏈簲鐢ㄧ爺绌剁儹鐐?瀵硅繖绫绘潗鏂欑殑鐮旂┒鍦ㄦ満鐞嗕笂搴旈泦涓湪绾崇背鏁堝簲瀵规潗鏂欐€ц兘鐨勫奖鍝嶃€傚湪搴旂敤涓婂簲鑰冭檻閲囩敤绠€鍗曘€佹湁鏁堢殑鏂规硶瀹炵幇绮樺湡鍦ㄨ仛鍚堢墿涓殑绾崇背鍒嗘暎涓庣撼绫虫晥搴旂殑浣撶幇,杩樺簲鑰冭檻鏉愭枡鐨勫啀鐢熷埄鐢ㄤ笌鍗敓闂浠ラ檷浣庢垚鏈?淇濇姢鐜銆?/span>銆?4銆?/span>

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鏍规嵁鏂囩尞涓柊鐨勭爺绌惰繘灞曪紝鎴戝綊绾冲嚭鎻愰珮闃婚殧鎬х殑鏂规硶鏈夛細鍏辫仛鏀规€с€佸叡娣锋敼鎬с€佹媺浼稿彇鍚戙€佽〃闈㈡秱瑕嗭紙SiOx锛夋敼鎬с€佷娇鐢ㄨ寕閲戝睘鍌寲鍓傘€佸姞娑叉櫠鑱氬悎鐗╋紙LCP锛夈€佺撼绫虫潗鏂欐敼鎬с€?/span>銆?8锝?4銆?/span>杩戝勾鏉ュ灞傚鍚堛€佸叡娣枫€佸叡鑱氥€佽捀闀€鎶€鏈彂灞曟瀬涓鸿繀閫熴€傚湪鍏跺畠鍩烘潗鐨勮杽鑶滀笂闀€瑕哠iOx(姘у寲纭?鍚庡埗寰楃殑鎵€璋撻晙瑕嗚杽鑶滆秺鏉ヨ秺鍙楀埌甯傚満閲嶈锛?/span>楂橀樆闅旀€у寘瑁呮潗鏂欏涔欑儻-涔欑儻閱囧叡鑱氱墿(EVOH)銆佽仛鍋忔隘涔欑儻(PVDC)銆佽仛閰?/span>鑳?PA)銆佽仛瀵硅嫰浜岀敳閰镐箼浜岄唶閰?PET)鐨勫灞傚鍚堟潗鏂欏強纭呮哀鍖栧悎鐗╄捀闀€钖勮啘绛夊緱鍒拌繘涓€姝ュ紑鍙戯紝鍏朵腑灏や互涓嬪垪浜у搧鏇翠负寮曚汉娉ㄧ洰锛歁XD6鑱氶叞鑳哄寘瑁呮潗鏂欙紱纭呮哀鍖栫墿钂搁晙钖勮啘绛夈€?/span>

鍦ㄦ煡闃呮枃鐚殑杩囩▼锛屾垜杩愮敤鐗╃悊鍖栧鍜岄珮鍒嗗瓙鐗╃悊鐨勫熀鏈師鐞嗘潵闃愯堪銆婂寘瑁呮潗鏂欏銆嬨€併€婅蒋鍖呰澶嶅悎鏉愭枡涓庡伐鑹恒€嬩腑闃婚殧鎬х殑闂锛屽闃婚殧鎬х殑璁よ瘑鍙樺緱鍏ㄩ潰銆佹繁鍏ワ紝鎴戠浉淇¢樆闅旀€х殑鐮旂┒杩樻湁寰堝ぇ鐨勫彂灞曠┖闂达紝浣嗛檺浜庤嚜韬按骞筹紝涓嶈冻涔嬪鎭宠鑰佸笀鎸囨锛?/span>

銆愬弬鑰冩枃鐚€?/span>

[1]鍛ㄧゥ鍏达紝浠绘樉璇?nbsp; 銆婂鏂欏寘瑁呮潗鏂欐垚鍨嬪強搴旂敤鎶€鏈€?nbsp;  鍖椾含锛氬寲瀛﹀伐涓氬嚭鐗堢ぞ  2004骞?鏈?/span>

[2]浼嶇娑?nbsp; 銆婅蒋鍖呰缁撴瀯璁捐涓庡伐鑹鸿璁°€?nbsp; 鍖椾含锛氬嵃鍒峰伐涓氬嚭鐗堢ぞ   2008骞?鏈?/span>

[3]姹熻胺  銆婂鍚堣蒋鍖呰鏉愭枡涓庡伐鑹恒€?nbsp; 鍗椾含锛氭睙鑻忕瀛︽妧鏈嚭鐗堢ぞ   2003骞?鏈?nbsp; P334锝?56

[4]鍛ㄧゥ鍏?nbsp; 銆婂鏂欏寘瑁呭埗鍝佺敓浜ф妧鏈棶绛斻€?nbsp; 鍖椾含锛氫腑鍥借交宸ヤ笟鍑虹増绀?nbsp;2002骞?鏈?nbsp;P214锝?17

[5]鍌呯尞褰╋紝娌堟枃闇炵瓑  銆婄墿鐞嗗寲瀛︺€嬶紙绗洓鐗堬級  鍖椾含锛氶珮绛夋暀鑲插嚭鐗堢ぞ 2005骞?鏈?/span>

[6]閲戞棩鍏夛紝鍗庡辜鍗?nbsp; 銆婇珮鍒嗗瓙鐗╃悊銆嬶紙绗笁鐗堬級 鍖椾含锛氬寲瀛﹀伐涓氬嚭鐗堢ぞ  2007骞?鏈?/span>

[7]璋㈡柊鑹恒€?/span>钖涘崕鑲?/span>  楂橀樆闅旀€у鏂欐潗鏂欏湪椋熷搧鍖呰涓殑搴旂敤 銆婂鏂欏寘瑁呫€?nbsp;2008骞?8鍗风1鏈?/span>

[8]璧垫睙  閫忔槑鍖呰涓庨樆闅旀€?nbsp;銆婂箍涓滃鏂欍€?nbsp;2006骞寸1鍗风2鏈?nbsp;P25锝?6

[9]寰愭鏋?nbsp;钖勮啘闃婚殧鎬х殑鍐冲畾鍙傛暟锛氭墿鏁g郴鏁?/span>  銆?/span>鍖呰涓栫晫銆?nbsp;2005骞寸2鏈?/span>

[10]璧垫睙  濡備綍鍙戞尌鍖呰闃婚殧鎬у淇濊川鏈熺殑淇冭繘浣滅敤  銆婂寘瑁呮娴嬨€?nbsp; 2007骞?鏈堢74鏈?/span>

[11]璧垫睙  楂橀樆闅旀€ф潗鏂欓€忔皵鎬ф祴璇曠殑鐗圭偣   銆婂箍涓滃寘瑁呫€?nbsp; 2005骞寸3鏈?/span>

[12]寮犱负鑳?nbsp; 闃婚殧鎬ф祴璇曟妧鏈渶鏂拌繘灞?nbsp;   銆婂鏂欏寘瑁呫€?nbsp;2007骞寸17鍗风3鏈?/span>  

[13]鐜嬫捣鐕?nbsp;  濉戞枡鍖呰鏉愭枡闃婚殧鎬ц兘鐨勬祴璇曟柟娉?nbsp;銆婂叏鐞冭蒋鍖呰宸ヤ笟銆?nbsp;2006骞?鏈?/span>  P51锝?4

[14]鐜嬪井灞便€佽档姹?nbsp; 钖勮啘閫忔皵鎬ф祴璇曠殑涓ょ鏂规硶姣旇緝——鍘嬪樊娉曚笌绛夊帇娉?nbsp; 銆婇鍝佸伐涓氱鎶€銆?008骞寸8鏈?nbsp;

[15]鍒樹集鍏?nbsp; 楂橀樆闅旀€VOH鏍戣剛 銆婄幇浠e鏂欏姞宸ュ簲鐢ㄣ€?nbsp;2000骞?鏈堢12鍗风4鏈?/span>

[16]鍐爲閾?nbsp; PET钖勮啘鐨勬€ц兘鍙婂叾鏀规€с€€鑱氶叝宸ヤ笟  銆€绗?2鍗风1鏈?nbsp; 2009骞?鏈?nbsp;P15锝?8

[17]鏉ㄦ按褰€佸倕鍜岄潚绛?nbsp; 楂橀樆闅旀€у鏂欏寘瑁呰啘鍙婂叾搴旂敤  銆?/span>鍖呰宸ョ▼銆?nbsp;2005骞寸26鍗风1鏈?/span>

[18] 楂橀樆闅旀€х撼绫冲鍚堟潗鏂欏強鍏跺埗鍝佺爺鍙戞垚鍔熴€婂厜瀛︾簿瀵嗘満姊般€?003骞寸1鏈?鎬荤88鏈燂級

[19]鍒樺浗淇?nbsp; 鏂板瀷楂橀樆闅旀€у寘瑁呮潗鏂?mdash;—GT钖勮啘   銆婂鏂欏寘瑁呫€?006骞寸16鍗风1鏈?/span>

[20]鍒橀檯娉?nbsp; 闃婚殧鎬у鏂欑殑鍙戝睍鐜扮姸 銆婂鏂欍€?nbsp;2004骞?3鍗风5鏈?/span>

[21]鍛ㄧゥ鍏?nbsp;楂橀樆闅旀€ц杽鑶滅殑鐢熶骇涓庢€ц兘銆婁腑鍥藉寘瑁呭伐涓氥€?001骞?鏈?nbsp;鎬荤86鏈?nbsp;P29锝?9

[22]鏉ㄦ灄锛岀帇缁忔  鍏辨贩鍚堝~鍏呮敼鎬ф妧鏈湪楂橀樆闅旀€у鏂欏寘瑁呮潗鏂欎腑鐨勫簲鐢ㄧ幇鐘?nbsp;銆婂寘瑁呭伐绋嬨€?004骞寸6鏈?/span>

[23]鏉滃畤鑺筹紝寮犲媷锛屾浌鍥借崳锛岃鏂囨墠  琛ㄩ潰鎺ユ灊鏀规€у鑱氫箼鐑杽鑶滈樆闅旀€х殑褰卞搷 銆?/span>Packaging Engineering銆?/span> Vo1锛?7 No锛?  2006锛?8  P47锝?9

[24]涓佽繍鐢熴€佸紶蹇楁垚銆佸彶閾侀挧  闃婚殧鎬ч珮鍒嗗瓙鏉愭枡鐮旂┒杩涘睍  銆奐ournal of Functional Polymers銆?/span>

Vol. 14锛?nbsp;No. 3 锛孲ep. 2001

[25]涓北澶у銆?/span>    闃婚殧鎬у鏂欏寘瑁呰杽鑶滅殑鍙戝睍  銆婂寘瑁呭伐绋嬨€?003骞?6鏈?nbsp;

[26]榛勬樊  闃婚殧鎬у鏂欏寘瑁呰杽鑶滅殑搴旂敤鍙戝睍  銆婂浗澶栧鏂欍€?007骞?5鍗风1鏈?nbsp;

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