宸ヤ綔鍘熺悊濡備笂鍥?鎵€绀猴紝鐜鎰熷簲鍨嬭仛鍚堢墿鍒锋帴鏋濈殑鏅鸿兘寮€鍏宠啘灏嗗鐜鍒烘縺(娓╁害銆?/span>pH鍊笺€佸厜銆佺數鍦恒€佺鍦恒€佸帇鍔?/span>绛?/span>)鍝嶅簲鍔熻兘鐨勮仛鍚堢墿鍒?/span>閫氳繃鎺ユ灊鍏变环閿悎浜庡井瀛旇啘锛岀幆澧冩潯浠剁殑寰皬鍙樺寲灏卞彲浣胯啘琛ㄩ潰鑱氬悎鐗╅摼鍙戠敓浜叉按鎬?/span>/鐤忔按鎬ц浆鍙橈紝瀵艰嚧鍒嗗瓙閾惧彂鐢熶几灞?/span>/鍗锋洸鐨勫彉鍖栵紝璧峰埌鑶滃瓟鍏?/span>/寮€鐨勫寲瀛﹂榾浣滅敤锛屼互姝ゆ潵鎺у埗娑蹭綋娴佽繃鑶滅殑閫熺巼銆?/span>鏍规嵁宸叉湁鐨勬劅搴斿師鐞嗚鎯?/span>鐜鍝嶅簲鍨嬫帶鍒剁殑鎺ユ灊鑱氬悎鐗╃殑鏅鸿兘寮€鍏?/span>鑶?/span>銆?/span>

                      鍥?font face="Times New Roman">3  鐜鎰熷簲鍨嬫帶鍒剁殑鑱氬悎鐗╁埛寮€鍏宠啘鐨?ldquo;寮€鍏充綔鐢?rdquo;绀烘剰鍥?/font>

鏁呭彲鏍规嵁澶栫晫鏉′欢鐨勫彉鍖栧彲灏嗙幆澧?/span>鎰?/span>搴斿瀷琛ㄩ潰鎺ユ灊鑱氬悎鐗╁埛鏅鸿兘寮€鍏宠啘鍒嗕负浠ヤ笅鍑?/span>绉?/span>鏉ヨ€冭檻锛?/span>

2.1 娓╁害鎰熷簲鍨嬭〃闈㈡帴鏋濊仛鍚堢墿鍒锋櫤鑳藉紑鍏宠啘

     鎵€璋撴俯搴︽劅搴斿瀷锛屽嵆褰撹啘鎵€澶勭殑鐜娓╁害鍙戠敓鍙樺寲鏃讹紝鑶滅殑褰㈢姸銆佹€ц兘绛夐殢涔嬪彂鐢熸晱閿愬搷搴旓紝琛ㄧ幇鍦ㄨ啘鐨勫惛姘撮噺鎴栧惛婧跺墏閲忋€佹憾鑳€姣斿湪鏌愪竴娓╁害鍙戠敓绐佸彉锛岃娓╁害绉颁负鏈€浣庝复鐣屾憾瑙ｆ俯搴︼紙The lowest critical solution temperature锛孡CST锛夈€?/span>銆?銆?/span>

     娓╁害鎰熷簲鍨嬫帶鍒剁殑鑱氬悎鐗╁埛鏀规€ф櫤鑳藉紑鍏宠啘鏄€氳繃鍦ㄨ啘琛ㄩ潰鎺ユ灊娓╁害鏁忔劅鎬ц仛鍚堢墿鍒峰埗澶囪€屾垚鐨勶紝鍏朵腑鍙楀埌骞挎硾鍏虫敞鐨勬槸娓╁害鏁忔劅鎬х殑鑱?/span>N-寮備笝鍩轰笝鐑叞鑳猴紙poly (N-Isopropyl acrylamide)锛孭NIPAm锛?/span>锛岀粨鏋勫紡濡備笅锛?/span>

     鐢辨枃鐚煡鑱?/span>N-寮備笝鍩轰笝鐑叞鑳虹殑LCST涓?/span>32鈩冿細 鍦?/span>LCST 浠ヤ笅锛岃仛N-寮備笝鍩轰笝鐑叞鑳虹殑姘ㄥ熀涓庢按褰㈡垚姘㈤敭锛屼互婧惰В鎬佸瓨鍦紝浣挎帴鏋濋摼澶勪簬浼稿睍鐘舵€侊紝姝ゆ椂鑶滃瓟鍏抽棴锛涘湪LCST 浠ヤ笂鏃讹紝璇ユ阿閿柇瑁傦紝鑱?/span>N-寮備笝鍩轰笝鐑叞鑳洪摼涓兎鍩虹殑鐤忔按浣滅敤澧炲己锛屼娇涔嬪浜庝笉婧惰В鐨勬敹缂╃姸鎬侊紝姝ゆ椂鑶滃瓟鎵撳紑銆傛晠璇ヨ啘鐨勬按閫氶噺鍦?/span>LCST闄勮繎浼氬嚭鐜扮獊璺冩€у崌楂橈紝鎺ユ灊閾剧殑LCST 灏辨槸鑶滃瓟寮€/鍏崇姸鎬佺殑杞彉娓╁害銆?/span>

     瑕佸疄鐜拌仛N-寮備笝鍩轰笝鐑叞鑳哄鑶滃瓟鐨勬俯鎺у寲瀛﹂榾浣滅敤锛屾帴鏋濈巼蹇呴』閫傚綋銆傚綋鎺ユ灊鐜囪繃浣庢垨杩囬珮鏃讹紝鎺ユ灊閾惧鑶滃瓟鎷ュ牭浣滅敤涓嶈冻鎴栬繃寮猴紝閮戒細浣胯啘閫氶噺闅忔俯搴﹀彉鍖栧箙搴﹀彉灏忋€傛澶栧彲閫氳繃鏀瑰彉鎺ユ灊閾剧殑LCST 瀹炵幇鑶滃瓟鍦ㄤ笉鍚屾俯搴︿笅鍏锋湁寮€鍏崇殑鐗规€с€?nbsp;   

2.2 PH鎰熷簲鍨嬭仛鍚堢墿鍒锋帴鏋濈殑鏅鸿兘寮€鍏宠啘

pH鏁忔劅鍨嬫槸鎸囪啘鐨勪綋绉互鍙婅啘鐨勬€ц兘闅忕幆澧僷H鍊笺€佺瀛愬己搴﹀彉鍖栫殑楂樺垎瀛愯啘銆?/span>杩欑被鑶滄槸灏嗚仛涓欑儻閰搞€佽仛4-涔欑儻鍚″暥绛夎仛鐢佃В璐ㄦ帴鏋濆湪鑶滀笂褰㈡垚鑱氬悎鐗╁埛鑰屽埗澶囩殑銆傚綋pH涓嶅悓鏃讹紝杩欎簺鑱氱數瑙ｈ川鍒?/span>浠ョ數绂绘垨闈炵數绂荤姸鎬佸瓨鍦紝鍥犳鏀瑰彉pH 鍙互鎺у埗鑶滃瓟鐨勫紑/鍏炽€?/span>渚嬪锛?/span>鑱氫笝鐑吀鎺ユ灊鑶滈€氶噺鍦ㄩ吀鎬ф椂楂橈紝涓€ф椂浣庯紝鎺ユ灊鐜囧鑶滈€氶噺褰卞搷澶э紱4-涔欑儻鍚″暥鎺ユ灊鑶滅殑閫氶噺鍦?/span>涓€ф椂楂橈紝閰告€ф椂浣庯紝鑶滈€氶噺鍙楁帴鏋濈▼搴﹀奖鍝嶄笉澶с€?/span>

鍙﹀锛?/span>鑱氱敳鍩轰笝鐑吀(PMAA)鍒嗗瓙閾句笂鍚湁澶ч噺鍙數绂荤殑-COOH鍩哄洟,鍥犺€屾槸涓€绫诲叿鏈塸H鍊兼晱鎰熺壒鎬х殑鏅鸿兘楂樺垎瀛?/span>銆?/span>褰撳€紁H浣庝簬鐢插熀涓欑儻閰哥殑pKa鏃? 鐢变簬楠ㄦ灦纰抽摼鍙婁晶閾剧敳鍩虹殑鐤忔按鐩镐簰浣滅敤,PMAA閲囧彇楂樺害鍘嬬缉绾垮洟鏋勮薄, 闅弍H鍊肩殑鍗囬珮, -COOH 瑙ｇ鑾峰緱璐熺數鑽? 搴撲粦闈欑數浣滅敤瀵艰嚧PMAA 杞寲涓鸿緝涓烘澗鏁ｇ殑浼稿睍鏋勮薄. 鎵€浠ユ敼鍙樻憾娑瞤H鍊煎皢寮曡捣涓欑儻閰哥被鑱氬悎鐗╃殑鏋勮薄鍙?/span>鍖?/span>銆?/span>

S. Dal绛?/font>浜?/span>銆?/span>8銆?/span>閫氳繃鍘熷瓙杞Щ鑷敱鍩鸿仛鍚堝弽搴?nbsp;(ATRP)鍚堟垚浜嗕竴绉嶆柊鍨嬬殑鍏锋湁pH鏁忔劅鐗规€х殑鍙屼翰鎬т簩宓屾鍏辫仛鐗?mdash;鑱氾紙鐢插熀涓欑儻閰?/font>-b-2-锛堜簩涔欏熀姘ㄥ熀锛夌敳鍩轰笝鐑吀涔欓叝锛?/font>, P(MAA-b-DEAm)锛岀粨鏋勫紡涓猴細

瀹為獙琛ㄦ槑锛屽綋婧舵恫pH<5.5锛堝搴斾簬鍏辫仛鐗╀腑PDEAm娈礜鍘熷瓙鐨勮川瀛愬寲锛夋椂锛?/span>鍏辫仛鐗╁舰鎴愪互鐤忔按鐨凱MAA涓烘牳锛岃川瀛愬寲鐨凱DEAm涓哄３鐨勭被鑳舵潫缁撴瀯锛涘綋pH > 9.2锛堝搴斾簬鍏辫仛鐗╀腑 PDEAm娈?nbsp;N瀹屽叏鍘昏川瀛愬寲锛屾鏃?nbsp;COOH瀹屽叏瑙ｇ涓?nbsp;COO-锛夋椂锛屽叡鑱氱墿鍙堜互鐤忔按鐨凱DEAm涓烘牳锛屼翰姘寸殑PMAA涓哄３鐨勭被鑳舵潫鏋勮薄褰㈠紡瀛樺湪锛涘綋 5.5 < pH < 9.2 鏃讹紝鐢变簬PDEAm閮ㄥ垎璐ㄥ瓙鍖栬€孭MAA鍙堥儴鍒嗚В绂伙紝姝ｈ礋鐢佃嵎涔嬮棿鐨勮ˉ鍋夸綔鐢ㄤ娇鍏辫仛鐗╁洟鑱氾紝婧舵恫閫忓厜鐜囬檷浣庛€?/span>

2.3 鍏?/span>鎰?/span>搴?/span>鍨嬭仛鍚堢墿鍒锋帴鏋濈殑鏅鸿兘寮€鍏宠啘

鍏夋劅搴斿瀷鏅鸿兘寮€鍏宠啘鍗抽€氳繃鍏夎緪灏勶紙鍏夊埡婵€锛変娇鑶滃彂鐢熶綋绉浉杞彉浠庤€屾敼鍙樿啘鎬ц兘鐨勯珮鍒嗗瓙鑶溿€傜敱鍏夊紩璧风殑鑱氬悎鐗?/span>鍒?/span>鏋勮薄鍙樺寲锛屽彲閫氳繃渚ч摼涓婂厜鏁忔€у姛鑳藉熀鐨勫紓鏋勫寲鏉ュ畬鎴愶紝濡傞『鍙嶅紓鏋勫寲鍙嶅簲銆?/span>鐢熻壊鍩哄洟鐨勭數绂荤瓑锛岃€岃繖浜涘張灏嗗鑷磋仛鍚堢墿閾炬€ц兘鐨勬敼鍙?/span>銆?/span>

鍏?/span>鎰?/span>搴?/span>鍨嬭仛鍚堢墿鍒锋帴鏋濈殑鏅鸿兘寮€鍏宠啘鍙皢鐢熻壊鍩?/span>鍥㈢洿鎺ュ紩鍏ュ埌鑱氬悎鐗╃殑渚ч摼涓?/span>鏉ュ疄鐜般€備竴绫诲吀鍨嬬殑鐢熻壊鍩?/span>鍥?/span>鏄?/span>鍋舵爱鑻被鐢熻壊鍥€傚伓姘嫰鍩哄洟鍦ㄧ传澶栧厜鐓у皠涓嬶紝鍙粠绋冲畾鐨勫弽寮?/span>(trans-)缁撴瀯杞彉涓鸿緝涓嶇ǔ瀹氱殑椤哄紡(cis-)缁撴瀯銆傚仠姝㈢収灏勫悗锛屽彂鐢熼€嗗悜鍙嶅簲锛岄『寮忕粨鏋勫張鍙浆鍙樹负鍙嶅紡缁撴瀯锛?/span>涓?/span>鍙鍏?/span>(λ>400nm)鐨勭収灏勪細鍔犻€熼€嗗悜鍙嶅簲鐨勮繘琛屻€?/span>

Seki绛夌爺绌朵簡鍚湁鍋舵爱鑻晶閾剧殑鑱氫箼鐑唶鍗曞垎瀛愯啘锛?/span>6Az10-PVA锛?/span>浣嶄簬姘撮潰涓婄殑鍗曞垎瀛愯啘缁忕传澶栧厜(365nm)鐓у皠鍜屽彲瑙佸厜(436nm)鐓у皠锛屼細琛ㄧ幇鍑洪潰绉殑鑶ㄨ儉鍜屾敹缂╋紝鏈€澶ц啫鑳€骞呭害鍙揪3 鍊嶏紝鏄洰鍓嶄负姝㈠凡鎶ラ亾鐨勬绫昏仛鍚堢墿闈㈢Н鏀瑰彉鐨勬渶澶у箙搴?/span>銆?銆?/span>銆傚彉褰㈢殑鏈虹悊琚涓烘槸锛氱传澶栧厜鐓у皠寮曡捣鐨勫厜寮傛瀯鍖栧弽搴斾娇鍋舵爱鑻熀鍥㈢殑鍋舵瀬鐭╁澶э紝鑱氬悎鐗╃殑鏋佹€у鍔狅紝浣挎按琛ㄩ潰鍜岃仛鍚堢墿浜х敓鍚稿紩鍔涳紝浠庤€屽紩璧烽潰绉啫鑳€銆傚啀缁忓彲瑙佸厜鐓у皠鏃讹紝鍙戠敓鍙€嗙殑杩囩▼锛屽紩璧烽潰绉敹缂┿€?/span>

鍥?font face="Times New Roman">4 琛ㄩ潰鎺ユ灊鑱氬悎鐗╁埛鏅鸿兘寮€鍏宠啘鐨勫厜鎰熷簲鍘熺悊绀烘剰鍥?/span>

2.4 鍏朵粬鎰熷簲鍨嬭仛鍚堢墿鍒锋帴鏋濈殑鏅鸿兘寮€鍏宠啘

鍓嶉潰浠嬬粛浜嗚緝瀹规槗瀹炵幇鐨勬俯搴︽劅搴斿瀷鍜宲H鎰熷簲鍨嬨€佸厜鎰熷簲鑱氬悎鐗╁埛鎺ユ灊鐨勬櫤鑳藉紑鍏宠啘锛岃繕鍙互妯悜鎷撳睍涓烘俯搴﹀拰pH鍙岄噸鎰熷簲鍨嬶紝鐢靛満銆佺鍦恒€佸帇鍔涙劅搴旂瓑绫诲瀷銆?/span>

    鏃㈢劧娓╁害鍜宲H鍊肩殑鎰熷簲鍨嬭緝鏄撳疄鐜帮紝鏁呭彲浠ヨ€冭檻娓╁害鍜?/span>pH鍊煎弻閲嶆晱鎰?/span>鍨嬭仛鍚堢墿鍒锋帴鏋濈殑鏅鸿兘寮€鍏宠啘锛屽嵆閫氳繃娓╁害鍜宲H鍊煎弻閲嶅洜绱犳潵璋冭妭鑶滅殑寮€鍏筹紝杩欑鏅鸿兘寮€鍏宠啘鍙兘鏇翠负鐏垫晱銆傜數纾佸満鎰熷簲鍨嬭仛鍚堢墿鍒锋帴鏋濈殑鏅鸿兘寮€鍏宠啘鏄寚鑶滅殑鐗规€у彈鐢靛満鎴栫鍦哄奖鍝嶈€屾敼鍙樼殑楂樺垎瀛愯啘銆傚帇鍔涙劅搴斿瀷鑱氬悎鐗╁埛鎺ユ灊鐨勬櫤鑳藉紑鍏宠啘鍒欐槸鏍规嵁鍘嬪姏鐨勫彉鍖栨潵鎺у埗鑶滅殑寮€鍏炽€?/span>

3銆?/span>琛ㄩ潰鎺ユ灊鑱氬悎鐗╁埛鐨勭幆澧冩劅搴斿瀷鏅鸿兘寮€鍏宠啘鐨勫簲鐢ㄥ睍鏈?/span>

琛ㄩ潰鎺ユ灊鑱氬悎鐗╁埛鐨勭幆澧冩劅搴斿瀷鏅鸿兘寮€鍏宠啘鍙互鍦ㄥ緢澶氶鍩熷簲鐢紝浠ヤ笅浠庤嵂鐗╂帶鍒堕噴鏀俱€佷紶鎰熴€佸垎绂荤瓑涓変釜鏈€涓昏鐨勬柟闈㈣繘琛屽睍鏈涳細

3.1 鍦ㄨ嵂鐗╂帶鍒堕噴鏀句腑鐨勭殑搴旂敤灞曟湜

 鑽墿鎺у埗閲婃斁鎶€鏈槸鐢熺墿鏉愭枡涓彂灞曟渶杩呴€熶篃鏄浜虹被鍋ュ悍璐＄尞鏈€澶х殑涓€涓鍩熴€?/span>鍏ㄧ悆鑽墿閲婃斁甯傚満閿€鍞涔熷湪绋虫涓婂崌锛屽湪鏁翠釜鑽搧甯傚満涓殑浠介涓嶆柇鎵╁ぇ銆傜洰鍓嶏紝鍏ㄧ悆閲婅嵂绯荤粺甯傚満澶х害涓?000浜跨編鍏冿紝鏈潵5骞村唴灏嗕互骞冲潎20%鐨勯€熺巼澧為暱锛屽埌2010骞村皢鍗犳暣涓尰鑽競鍦虹殑20%浠ヤ笂锛岄攢鍞鍙揪2200浜跨編鍏冦€傚湪涓栫晫鍚勫浗涓紝缇庡浗銆佹娲茶鍥藉拰鏃ユ湰鐨勯噴鑽郴缁熶骇鍝侀攢鍞鍗犲叏鐞冩暣涓噴鑽郴缁熷競鍦虹殑90%浠ヤ笂锛屽叾涓編鍥藉崰56%锛屾娲插悇鍥藉崰29%锛屾棩鏈崰9%銆?/span>杩欒〃鏄庝簡鑽墿閲婃斁浣撶郴鐨勫箍闃斿簲鐢ㄥ墠鏅€?/span>
     闀挎湡浠ユ潵锛屽尰鑽晫閮藉笇鏈涜兘鎵惧埌涓€绉嶆柟娉曪紝鍙互鍦ㄩ渶瑕佺殑鏃跺€欏皢闇€瑕佺殑鑽墿閲忔姇鏀惧埌闇€瑕佺殑浜轰綋鍣ㄥ畼銆傚埄鐢ㄦ俯搴︽劅搴斿瀷鎴杙H鎰熷簲鍨嬬殑鏅鸿兘寮€鍏宠啘鍙互瀹炵幇鐥呯伓鍛ㄥ洿娓╁害鎴杙H绛夊紓甯稿彉鍖栫殑鑷姩鎰熺煡锛岃嚜鍔ㄩ噴鏀炬墍闇€閲忕殑鑽墿銆傚綋韬綋姝ｅ父鏃讹紝鑽墿鎺ч噴绯荤粺鎭㈠鍘熸潵鐨勭姸鎬侊紝閲嶆柊鎶戝埗閲婃斁銆?/span>

 鍚岀悊锛岀敱鐗瑰畾褰㈢姸鐨勮仛鍚堢墿鍒锋帴鏋濈殑鐜鎰熷簲鍨嬫櫤鑳藉紑鍏宠啘鍦ㄧ粏鑳炵敓闀夸笌姝讳骸鐨勬帶鍒躲€佷豢鐢熻杽鑶滄潗鏂欏櫒绛夋柟闈篃鍏锋湁骞块様鐨勫簲鐢ㄣ€?/span>

3.2 鍦ㄤ紶鎰熶腑鐨勫簲鐢ㄥ睍鏈?/span>

 琛ㄩ潰鎺ユ灊鑱氬悎鐗╁埛鐨勫悇绉嶇幆澧冩劅搴斿瀷鏅鸿兘寮€鍏宠啘浣滀负鏅鸿兘楂樺垎瀛愶紝鑳藉搷搴斿閮ㄥ埡婵€娓╁害銆佺銆佸姏銆?/span>pH鍒烘縺鐨勫井灏忓彉鍖栥€傚埄鐢ㄤ紶鎰熷櫒鍙互灏嗚繖浜涘彉鍖栫殑鐗╃悊閲忔垨鍖栧閲忚浆鎹负鐢典俊鍙疯繘琛屾娴嬨€?/span>

 2008骞村叏鐞冧紶鎰熷櫒甯傚満瀹归噺涓?06浜跨編鍏冿紝鏍规嵁鍏ㄧ悆浼犳劅鍣ㄥ競鍦虹殑棰勬祴锛岄璁?010骞村叏鐞冧紶鎰熷櫒甯傚満鍙揪600浜跨編鍏冧互涓娿€傝皟鏌ユ樉绀猴紝涓滄銆佷簹澶尯鍜屽姞鎷垮ぇ鎴愪负浼犳劅鍣ㄥ競鍦哄闀挎渶蹇殑鍦板尯锛岃€岀編鍥姐€佸痉鍥姐€佹棩鏈緷鏃ф槸浼犳劅鍣ㄥ競鍦哄垎甯冩渶澶х殑鍦板尯銆?/span>
銆€銆€ 涓€浜涗紶鎰熷櫒甯傚満姣斿鍘嬪姏浼犳劅鍣ㄣ€佹俯搴︿紶鎰熷櫒銆佹祦閲忎紶鎰熷櫒銆佹按骞充紶鎰熷櫒宸茶〃鐜板嚭鎴愮啛甯傚満鐨勭壒寰併€傛祦閲忎紶鎰熷櫒銆佸帇鍔涗紶鎰熷櫒銆佹俯搴︿紶鎰熷櫒鐨勫競鍦鸿妯℃渶澶э紝鍒嗗埆鍗犲埌鏁翠釜浼犳劅鍣ㄥ競鍦虹殑21%銆?9%鍜?4%銆?/span>
銆€銆€ 鐩墠锛屽叏鐞冪殑浼犳劅鍣ㄥ競鍦?/span>杩?/span>鍦ㄤ笉鏂彉鍖栫殑鍒涙柊涔嬩腑鍛堢幇鍑哄揩閫熷闀跨殑瓒嬪娍銆傛湁鍏充笓瀹舵寚鍑猴紝浼犳劅鍣ㄩ鍩熺殑涓昏鎶€鏈皢鍦ㄧ幇鏈夊熀纭€涓婁簣浠ュ欢浼稿拰鎻愰珮锛屽悇鍥藉皢绔炵浉鍔犻€熸柊涓€浠ｄ紶鎰熷櫒鐨勫紑鍙戝拰浜т笟鍖栵紝绔炰簤涔熷皢鏃ョ泭婵€鐑堛€傛柊鎶€鏈殑鍙戝睍灏嗛噸鏂板畾涔夋湭鏉ョ殑浼犳劅鍣ㄥ競鍦猴紝姣斿浼犳劅鍣ㄣ€佹櫤鑳戒紶鎰熷櫒绛夋柊鍨嬩紶鎰熷櫒鐨勫嚭鐜颁笌甯傚満浠介鐨勬墿澶с€?/span>

3.3 鍦ㄥ垎绂讳腑鐨勫簲鐢ㄥ睍鏈?/span>

     鐢辩幆澧冨搷搴旀€ч珮鍒嗗瓙鍒跺鐨勫姛鑳借啘鏉愭枡鍙湜鐢ㄤ簬璁稿棰嗗煙姹℃按澶勭悊銆侀噸閲戝睘鍒嗙銆佽泲鐧借川鍒嗙銆佺粏鑳炶劚闄勩€佺粍缁囧伐绋嬬瓑鏂归潰銆?/span>銆?銆?/span>灏嗚仛鍚堢墿鎺ユ灊閾句笌鑶滆〃闈?/span>鍖栧閿悎鍚?/span>锛屽叾浼樼偣鍦ㄤ簬寰瓟鑶滃彲浣滀负鏈烘鏀拺鑰屾帴鏋濋珮鍒嗗瓙閾剧敱浜庣幆澧冨埡婵€鑰屽彂鐢熺殑鏋勮薄鍙樺寲鍒欏鑷磋啘娓楅€忔€ц兘鐨勬敼鍙樸€?/span>
     鏍规嵁銆?008骞翠腑鍥借啘甯傚満甯傚満鐮旂┒棰勬祴鎶ュ憡銆嬶紝闅忕潃鎴戝浗鍥芥皯缁忔祹鐨勫彂灞曞拰浜烘皯鐢熸椿姘村钩鐨勬彁楂橈紝鑶滄妧鏈殑搴旂敤棰嗗煙灏嗕笉鏂墿澶э紝鍒?010骞存垜鍥界殑鑶滅瀛︿笌鎶€鏈按骞冲皢杈惧埌鍥藉90骞翠唬鍚庢湡鐨勬按骞筹紝灞曟湜“鍗佷竴浜?rdquo;锛岃啘宸ヤ笟甯傚満鍓嶆櫙鑹ソ銆?ldquo;鍗佷竴浜?rdquo;鏈熼棿骞村潎澧為€熺户缁繚鎸佸湪15%宸﹀彸锛?015骞达紝鑶滃競鍦洪渶姹傚彲鏈涜秴杩?00浜垮厓锛岀害鍗犱笘鐣屾€婚噺鐨?0-15%銆?/span>
     闅忕潃鑶滅瀛︿笌鎶€鏈殑鍙戝睍锛岃〃闈㈡帴鏋濊仛鍚堢墿鍒风殑鐜鎰熷簲鍨嬫櫤鑳藉紑鍏宠啘鐨勫垎绂诲姛鑳藉皢鑾峰緱鏇村鐨勫疄闄呭簲鐢紝濡備汉浣撳櫒瀹樸€侀椄鑶滐紙鎴栫О瀛斿緞鍙彉鑶滐紝鏅鸿兘鍨嬪垎绂昏啘锛変互鍙婃椿鎬ц緭閫佽啘绛夈€備腑鍥界殑鑶滃競鍦烘槸宸ㄥぇ鐨勶紝鍓嶆櫙鏄箍闃旂殑锛岀爺鍒跺紑鍙戞柊鐨?/span>鏅鸿兘鑶滄槸鐮旂┒鐨勯噸瑕佺儹鐐广€?/span>

銆愮粨鏉熻銆?/span>

     鎬讳箣锛岃仛鍚堢墿鍒锋帴鏋濈殑鐜鎰熷簲鍨嬫櫤鑳藉紑鍏宠啘鍦ㄨ〃闈㈡敼鎬ф垨淇グ鏂归潰锛?/span>璧嬩簣浜嗗垎绂?/span>鑶滆澶氭柊棰栫殑鍔熻兘锛屾嫇瀹戒簡鍒嗙鑶滅殑搴旂敤棰嗗煙锛屼娇鍏跺叿鏈夊法澶х殑娼滃湪搴旂敤鍓嶆櫙锛?/span>涓鸿В鍐宠啘绉戝鎶€鏈毦棰樺甫鍏ョ敓鏈哄拰娲诲姏銆傚浜庤〃闈㈡帴鏋濊仛鍚堢墿鍒风殑鐜鎰熷簲鍨嬫櫤鑳藉紑鍏宠啘锛岀洰鍓嶇殑鐞嗚绐佺牬鐐瑰湪浜庯細

鈶?nbsp;鐜鍝嶅簲鎬ф潗鏂欐帴鏋濇潯浠朵笌鍝嶅簲鎬ц兘涔嬮棿鐨勫叧绯?/span>锛?/span>闇€瑕佽繘涓€姝ョ殑绯荤粺鐮旂┒锛?/span>

鈶?nbsp;鏂板瀷鐨勫叿鏈夌幆澧?/span>鍒烘縺鍝嶅簲鎬х殑鑱氬悎鐗╁埛杩樻湁寰呭紑鍙戠瓑鏂归潰杩橀渶瑕佸仛澶ч噺鐨勫伐浣?/span>銆?/span>

     鍥犳浣胯啘琛ㄩ潰鐨勮仛鍚堢墿鍒峰叿鏈夐瀹氱殑寰缁撴瀯锛屽皢鎴愪负浠婂悗鐮旂┒鐨勬牳蹇冦€?/span>

銆?/span>鑷磋阿銆?/span>

     鎰熻阿鏉庝寒鑰佸笀鍜?7绾х爺绌剁敓鏌礊灏嗗闀跨殑鎸囧鍜屽府鍔╋紒鎴戜究閫夋嫨杩欎釜瑙掑害鎬濊€冨垱鏂扮偣銆?/span>

銆愬弬鑰冩枃鐚€?/span>

[1]褰収,鐜嬪,鏉ㄥ┓濠?涓ヨ枃,绋嬫椂杩?/span>.  鍘熷瓙杞Щ鑷敱鍩鸿仛鍚堟硶鍒跺鑱氬悎鐗╁埛  銆?/span>鏉愭枡瀵兼姤銆?/span>2005骞?鏈堢19鍗风3鏈?/span>73-76椤?/span>

[2]鍒樻尟姊?/span>锛?/span>寰愬織搴?/span>锛?/span>鎴存竻鏂?/span>.  鐜鍝嶅簲鍨嬪井瀛旇啘鐮旂┒杩涘睍 銆?/span>鍖栧閫氭姤銆?/span> 2002骞寸65鍗?/span>

[3]Stephen G. Boyes, Anthony M. Granville, Marina Baum, Bulent Akgun,Brian K. Mirous, William J. Brittain Polymer brushes—surface immobilized polymers  銆?/span>Surface Science銆?/span> 570 (2004)1–12椤?/span>

[4]寮犵,鏉庢枃,寮犻樋鏂?/span>.  鑱氬悎鐗╁垎瀛愬埛鐨勫悎鎴愪笌搴旂敤 銆?/span>鍖栧杩涘睍銆?nbsp;2006骞?/span>8鏈堢18鍗风7/8鏈?/span>940-949椤?/span>

[5]鍒樻窇鑺?/span>锛?/span>宕斿疂鑷?/span>锛?/span>鐜嬪疂杈?/span>.  銆?/span>鑶滆〃闈㈡帴鏋濊仛鍚堢墿鍒风殑鍚堟垚涓庡簲鐢?/span>銆?nbsp; 鍖栧閫氭姤 2005骞寸68鍗?/span>

[6]闄堣帀.  銆婃櫤鑳介珮鍒嗗瓙鏉愭枡銆嬶紙绗竴鐗堬級  鍖椾含锛氬寲瀛﹀伐涓氬嚭鐗堢ぞ  2005骞?鏈?/span>

[7]鐜嬫捣涓?/span>,鏉庤壋,瑜氳壇閾?/span>,闄堟枃姊?/span>.  PH鍊间笌娓╁害鎰熷簲鍨嬫櫤鑳藉紑鍏宠啘鐨勭爺绌?/span>  銆?/span>杩囨护涓庡垎绂?/span>銆?nbsp;2003骞寸13鍗?/span> 绗?鏈?/span>

[8]閲戞窇钀?/span>,鏌虫槑鐝?/span>绛?  鏅鸿兘楂樺垎瀛愬強姘村嚌鑳剁殑鍝嶅簲鎬у強鍏跺簲鐢?/span>  銆?/span>鐗╃悊鍖栧瀛?/span>鎶ャ€?nbsp;2007骞寸23鍗风3鏈?/span>438-446椤?/span>

[9]绉︾憺涓?/span>锛?/span>鏈卞厜鏄?/span>锛?/span>鏉滃畻缃?/span>锛?/span>鍛ㄦ捣宄?/span>.   鍏夋晱褰㈢姸璁板繂鑱氬悎鐗?/span>  銆婂寲瀛﹂€氭姤銆?nbsp;2004骞寸67鍗风6鏈?/span>