浜轰滑閮借涓虹涓€绫荤瀛愭恫浣撳惛姘存€ч潪甯稿己锛岃繖鏄紭浜庝汉浠紑濮嬬爺绌剁涓€绫绘隘鍖栭摑浣撶郴鐨勭瀛愭恫浣撳緱鍑虹殑缁撴灉锛屼娇寰楁垜浠湪鐮旂┒杩欎竴绫荤瀛愭恫浣撴椂閮藉繀椤诲湪鎵嬪绠变腑鎿嶄綔銆備絾鏍规嵁1-涓佸熀寮傚柟鍟夋湁鏈洪槼绂诲瓙涓庢隘鍖栭晸瀵规按闈炲父绋冲畾鎬э紝鎵€浠ヨ瘯鍥炬帰璁?/span>1-涓佸熀寮傚柟鍟夋隘鍖栭摕褰㈡垚鐨勭瀛愭恫浣撳姘寸殑绋冲畾鎬э紝缁撴瀯鐮旂┒鍙戠幇瀹冨姘寸殑绋冲畾鎬т笌閲戝睘闃寸瀛愮殑缁撴瀯鏈夊叧銆傜浉瀵逛笌涓夋隘鍖栭晸鍜屼笁姘寲閾熻绋冲畾寰楀銆傜涓€绫荤瀛愭恫浣撶敱浜庢帰璁ㄥ挭鍞戠被鏈夋満闃崇瀛愬绂诲瓙娑蹭綋缁撴瀯鐨勪綔鐢紝閫夋嫨1-涓佸熀-寮傚柟鍟夊澶ч槼绂诲瓙π绂诲煙浣撶郴锛岀敱浜庨噾灞炵洂鍜屾湁鏈洪槼绂诲瓙缁勬垚瀵圭啍鐐规湁寰堝ぇ鐨勫奖鍝?/span>锛屽綋缁勬垚1锛?/span>1鏃跺娓╂潯浠朵笅鍛堢爺绌朵簡姘村垎瀛愬璇ョ瀛愭恫浣撶粨鏋勫奖鍝嶏紝(BIQL)2 In Cl5鐨勬櫠浣撶粨鏋勶紝缁撴瀯鍙?/span>姘村垎瀛愬绂诲瓙娑蹭綋1-涓佸熀-寮傚柟鍟夋隘鍖栭摕缁撴瀯鐨勫奖鍝嶅彲浠ヤ粠鑾峰緱鐨?/span>X-灏勭嚎鏅朵綋琛嶅皠鐨勭粨鏋勫垎鏋愬緱鍒扮殑鏅朵綋缁勬垚涓?/span>[(BIQL)2(InCl4·2H2O)]銆傛櫠浣撶粨鏋勫睘浜庝笁鏂滄櫠绯?/span>P-1绌洪棿缇わ紝褰撴棤姘寸姸鎬佹椂绂诲瓙娑蹭綋涓槾绂诲瓙鏄?/span>InCl5-锛屽綋鏈夊皯閲忔按鍒嗗瓙杩涘叆绂诲瓙娑蹭綋缁撴瀯涓紝闃寸瀛愰儴鍒嗘垚涓烘櫠浣撶粨鏋勪腑Cl-绂诲瓙涓庡拰2涓按鍒嗗瓙涓?/span>In锛?/span>III锛夊舰鎴愬叚閰嶄綅鐨勯槾绂诲瓙鍙婁竴涓父绂荤殑姘笌2涓紓鍠瑰晧闃崇瀛愬憟鐢典腑鎬э紝鍏朵腑涓や釜寮傚柟鍟夐槼绂诲瓙鐨勭粨鏋勫钩闈㈠す瑙掍负81°銆傛櫠浣撲腑瀛樺湪鐨勪竴涓父绂荤殑姘村垎瀛愪笌(InCl4·2H2O)-绂诲瓙涓殑姘強Cl-褰㈡垚涓や釜姘㈤敭锛屾父绂荤殑Cl-绂诲瓙涓?/span>(InCl4·2H2O)-绂诲瓙涓殑涓や釜姘村垎瀛愬強娓哥鐨勬按鍒嗗瓙褰㈡垚姘㈤敭銆?/span>