ABS/PBT合金的研究进展

聚对苯二甲酸丁二醇酯（PBT ） 是由在20世纪70年xx发并工业化生产的一类较新的热塑料工程塑料，具有以下特性：（1）结晶速度快，可快速成型；（2）吸水率低，电气性能优异且随温湿度变化小；（3）耐候性好，适于户外使用，且耐药品性优异；（4）力学性能优良。纯PBT树脂有优异的冲击韧性，，经玻纤增强后，不仅可使缺口敏感性得到改善，而且还能使热变形温度大大提高，弯曲模量成倍增长；（5）。由此可见，PBT综合性能{zy1}，因而已成为通用工程塑料中工业化最晚而发展速度最快的1个品种。

    PBT的缺点为：（1），尺寸稳定性差。虽经增强后可改善收缩率，但容易发生翘曲，同时使无缺口冲击强度下降；（2）。由于PBT存在着这两个突出缺点，因而限制了它的应用。

    ABS树脂是目前产量{zd0}，应用最广泛的塑料，价格也比较便宜。它不仅具有韧、硬、刚相均衡的力学性能，而且具有较好的尺寸稳定性、表面光泽度、耐低温性、着色加工性和加工流动性。可以预计，将ABS/PBT共混，可以制得性能优异的塑料合金，实现树脂高性能化。

    1 国外研究进展

    ABS/PBT合金充分利用了PBT的结晶性和，材料具有优良的成型性、尺寸稳定性和耐药品性，缺口冲击强度较PBT大大提高，因而其新产品层出不穷，国外许多公司都投入了ABS/PBT合金商品化的开发工作。

  是通用注塑级，产品具有优异的冲击强度（32.3KJ/m2），熔融指数高，尺寸稳定性良好，收缩率为0.5~0.8%，较纯PBT 2.0%的收缩率大大改善。其典型应用是打字机和复印机外壳、汽车保险壳及防撞件的制造等。HF-5600F主要应用于消费电子产品制造领域，为阻燃等级。它充分利用了PBT易于阻燃、耐磨性好、电气性好的特点，其典型应用是制造DVD以及。PBT较低的摩擦系数，改良的尺寸稳定性可以保证托盘在轨道上方便滑动。GP-5106F1，GP-5200B是玻纤增强型，它有较高的热变形温度，并改善了玻纤增强PBT的翘曲性能，适用于生产电子、电器元件及接插件。

    汽车内饰件对塑料的要求是低光泽、防刮伤、耐冲击。GE公司在2002年9月份宣布新开发成功一种新型的满足以上要求的材料Cytra ABS/PBT，该材料不仅具有传统的汽车内饰用PP、ABS、PC/ABS等材料优良的力学性能，而且具有 更高的冲击强度及高、低温下的尺寸稳定性。其 特点如下：（1）极高的冲击强度；（2）；（3）耐化学药品性优良，对汽油、油脂、洗 涤剂、脂肪族碳氢化合物溶剂、香水瓶及化妆品稳定；（4）；（5）低光泽及耐候。该材料通过控制ABS聚合时丁二烯橡胶的 粒径，制得低光泽的ABS/PBT合金，并在造粒 时直接着色，可以免去涂装亚光油漆，节省成 本。其中的Cytra XCT100密度为1.1g/cm3，缺 口冲击强度达853.9J/m ，弯曲模量为 2168MPa，主要应用于生产盘表壳、仪表板、安全气囊盖、座椅扶手等。Cytra XCT200为高 冲击ABS/PBT/PC三元合金，其密度为1.22g/cm3，缺口冲击强度800J/m，应用于对冲击强度有严格要求的气囊外壳、A、B、C立柱、除霜 出风格栅、操纵台等的生产。

    2 国内研究进展

    国内ABS/PBT合金的开发尚未见工业化报道，为打破国外大公司在该专用料领域的垄断地位，缩小与国外在这一技术领域上的差距，国内也有公司进行了ABS/PBT合金的国产化研制工作。

    2.1 体系相容性研究

    ABS/PBT合金是不相容性体系，将，材料性能较差，因此ABS/PBT合金研制的关键之一是添加合适的相容剂。

    2.2 形态与性能的关系

    我们所做的试验表明：ABS/PBT合金的性能不仅依赖于组分的相对比例及分布，还依赖于ABS接枝橡胶粉中橡胶相的粒径、形态结构、相对分子质量及其中丙烯腈的含量。丙烯腈的含量同样影响体系的相容性，使用高分子量的ABS接枝橡胶粉与PBT共混，在橡胶含量相同时，其热变形温度更高，冲击强度更大；添加相容剂，可以改善界面相容状况；合适的橡胶粒径，可使增韧效果有一极大值。

    用电镜可以看出ABS/PBT合金为三相体系，。因此，丙烯腈含量的多少是影响ABS/PBT界面粘接的关键因素之一。选用高分子量的ABS接枝粉，可以开发具有较高熔体强度的吹塑级ABS/PBT合金，用于汽车尾翼和保险杠的生产，而提高ABS接技粉中的橡胶粒径，则可以降低ABS/PBT合金的光泽，开发亚光牌号。

    3 发展前景

    ABS/PBT合金是一类性能优良的工程塑料合金，国外对它的开发颇为活跃，尤其在汽车行业，ABS/PBT合金优良的加工流动性和极高的冲击强度，对汽车大型注塑件具有重要意义。GE公司开发的低光泽牌号可以作为，其冲击强度远远高于矿物填充PP，ABS，流动性优于ABS、PC/ABS，而PBT的耐磨性则贡献了优秀的耐刮伤性能，因而这是一种较为理想的汽车内、外饰材料。ABS/PBT合金的良好电气性能和耐磨性、耐化学品性，使其在电子消耗品及包装行业也有着广泛的应用。然而，在国内ABS/PBT合金尚未见产业化报道。

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Royalite R71/920
Royalite R922
RTP Compounds 2500

RTP Compounds 2500 FR A
RTP Compounds 2500 FR-110
RTP Compounds 2500 FR-3010
RTP Compounds 2500 HF A
RTP Compounds 2500 TFE 10
RTP Compounds 2500 TFE 15 FR
RTP Compounds 2500 TFE 20 FR
RTP Compounds 2500 TFE 5
RTP Compounds 2500 UV
RTP Compounds 2500.5
RTP Compounds 2501
RTP Compounds 2501 A
RTP Compounds 2501 FR
RTP Compounds 2502
RTP Compounds 2502 FR
RTP Compounds 2503
RTP Compounds 2503 A

RTP Compounds 2505 FR
RTP Compounds 2507
RTP Compounds 2560.75 FR
RTP Compounds 2563
RTP Compounds 2563 FR
RTP Compounds 2581
RTP Compounds 2581 FR
RTP Compounds 2581 HEC FR
RTP Compounds 2581.3
RTP Compounds 2581C HEC
RTP Compounds 2581C HEC FR

RTP Compounds 2585
RTP Compounds 2585 FR
RTP Compounds 2587
RTP Compounds 2587 FR
RTP Compounds 2599 X 61232 A FR
RTP Compounds 2599 X 65037 FR A
RTP Compounds 2599 X 67122
RTP Compounds 2599 X 87260 B
RTP Compounds 2599 X 96121
RTP Compounds 2599X87260C
RTP Compounds EMI 2560.5
RTP Compounds EMI 2560.5 FR
RTP Compounds EMI 2560.7
RTP Compounds EMI 2560.75
R
RTP Compounds EMI 2562
RTP Compounds EMI 2562 FR
RTP Compounds EMI 2580.5
RTP Compounds EMI 2580.5 C FR
RTP Compounds EMI 2580.5 FR
RTP Compounds EMI 2580.7
RTP Compounds EMI 2580.7 FR
RTP Compounds EMI 2581
RTP Compounds EMI 2581 FR
RTP Compounds EMI 2581.2 FR
RTP Compounds EMI 2581.4
RTP Compounds EMI 2581.4C FR
RTP Compounds EMI 2581C FR
RTP Compounds EMI 2582
RTP Compounds EMI 2582 FR
FR
RTP Compounds ESD A 2500
RTP Compounds ESD A 2580
RTP Compounds ESD A 2580 FR
RTP Compounds ESD C 2500
RTP Compounds ESD C 2580
RTP Compounds ESD C 2580 FR
VAMPALLOY 0023 V0 A
VAMPALLOY 0023 V0 E
VAMPALLOY 0023 V0 F
VAMPALLOY 0023 V0 G
VAMPALLOY 0024 V0 11
VAMPALLOY 0024 V0 13
Verolloy S1100
Verolloy S1210
Verolloy S1220
Verolloy S1230
Verolloy S1500
Verolloy S3100
/ABS 1078
ASTALOY™ MDA257
Boltaron 6500
Boltaron 6530
Kumho ABS HFB-701
Kumho ABS HFB-702
Royalex Royalex
Royalite R540M
Royalite R57
Royalite R59
Royalstat R63
Royalstat R632
Boltaron 1165
MDI ABS AB-925
MDI ABS AB-928
MDI ABS AB-950
SENOSAN® AM50C Solar Plus
ColorFast™ NYA1000

EXCELLOY AK12G20 (Cond)
EXCELLOY AK12G20 (Dry)
EXCELLOY AK15 (Cond)
EXCELLOY AK15 (Dry)
Schulablend® M/MK (Cond)
Schulablend® M/MK (Dry)
Sicoblend N108
Sicoblend N8065
TECHNIACE® TA-1500
20
TEREZ PA/ABS Blend 3610
TEREZ PA/ABS Blend 3610 GF2
TEREZ PA/ABS Blend 3610 GK10
TEREZ PA/ABS Blend 3610 UV
TEREZ PA/ABS Blend 3614
TEREZ PA/ABS Blend 3620
Toyolac® SX01
Triax® 1180 (Cond)
Triax® 1180 (Dry)
Triax® 1185
Triax® 1220 S (Cond)

Triax® 1408 GF (Cond)
Triax® 1408 GF (Dry)
Triax® DP 3157 (Cond)
Triax® DP 3157 (Dry)
Triax® DP 3159
Triax® KU 2-3050 (Cond)
Triax® KU 2-3050 (Dry)
Triax® KU 2-3154 (Cond)
Triax® KU 2-3154 (Dry)

TUFFLOY 1120 (Dry)
CCP PBT 7300 H
CCP PBT 7300 H
CCP PBT 7320 H
CCP PBT 7320 H
CCP PBT 7320 V
CCP PBT 7320 V
CCP PBT 7330 V
CCP PBT 7330 V
CCP PBT 7500 H
CCP PBT 7500 H
CCP PBT 7530 H
CCP PBT 7530 H
CCP
ColorFast™ PBA2000
ColorFast™ PBA2000
Duranex® 304SA
Duranex® 361SA
Duranex® 601SA
Duranex® 652SA
Duranex® 701SA
Duranex® 711SA
Duranex® 733LD
Duranex® 750LD

Staroy VB-3100G
TECHNIACE® TB-1701
TECHNIACE® TB-1801
TEREZ PBT/ABS Blend 4240/20
Toyolac® VX10
UMG ALLOY® TV40A
UMG ALLOY® TX10A
UMG ALLOY® TX40A
UMG ALLOY® TX64D
UMG
Carbotex K-2000
Carbotex K-3000
Carbotex K-3000
Carbotex K-5000
Carbotex K-5000
Carbotex K-5100
Carbotex K-5100
Carbotex K-5500
Carbotex K-5500
CELEX™ 5200HF.IM
CELEX™ 5200HF.IM

Cheng Yu C1200
Cheng Yu C1300
Cheng Yu C1300
Cheng Yu C660F
Cheng Yu C660F
Cheng Yu C6700
Cheng Yu C6700
Cheng Yu C6800
Cheng Yu C6800
ColorFast™ FRPA100X
ColorFast™ FRPA100X
ColorFast™ PAHF
ColorFast™ PAHF

CP PRYME® PC/ABS PCA300
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