Shell Glycol Ethers壳牌乙二醇醚Physical propertiesOXITOL,PROXITOL,OXITOLShellOXITOL,PROXITOL,OXITOLShell

物理性质
乙二醇醚及其酯
无色，高稳定的液体沸腾
点和温和的气味。随着既有醚
组和酒精或酯组
同样的分子，它们可以混合使用
水和其他溶剂，并
结合强大的溶解
低波动性的特点。
这种属性的组合使
一些主要表现乙二醇醚
特征为溶剂型系统
其中包括：
●与水相容性
●兼容1
广泛的极地
和非极性溶剂
●高功率溶剂
●低波动
●轻度气味
●聚结
壳牌乙二醇醚：
OXITOL *和PROXITOL *
* OXITOL和PROXITOL是商标
皇家荷兰/壳牌集团的公司。
多功能，高性能的设计以满足溶剂
增加技术和环境要求的溶剂基
配方。乙二醇醚是非常适合新
低芳烃，高固体和水的技术驱动
通过立法和消费者的需求。化妆品/个人护理
溶剂和耦合性能
乙二醇醚是利用在许多化妆品
和化妆品配方。它们可以
用于稳定乳液用乳液，
防止颗粒的活性成分
从辍学的悬浮液。
这有助于维持审美
该产品的外观和可
增加货架寿命。他们还可以
用于改善水驱避
在屏幕的产品，如太阳。
工业和家用清洁剂
乙二醇醚可用于所有类型的
清洁工人。他们降低表面张力和
有良好的偶联剂。工作在
以表面活性剂的同时，它们促进
润湿的表面上，渗透
土壤，并有助于暂停在水土
直到它被擦拭或冲洗了。
乙二醇醚的选择取决于
清洁型应用，其性质
土壤和溶解度和蒸发
率要求。共混物和乙二醇醚
表面活性剂，可用于优化
清洗性能和效率。
涂料和油墨清洗剂
汽车{wn}
工业维护玻璃
线圈烤箱
工业设备及电器
制炼渍住户
建筑凹版印刷
海洋Flexograph
航天丝网印刷
胶印塑料底漆
树脂的配方
着色剂
稀释剂
专业油漆
图一：
主要应用
乙二醇醚可用于广泛的应用范围
而且涉及的行业广泛的范围（见图1）。
其中的主要应用领域：
壳牌产品研究所。号
丁基OXITOL 111-76-2
丁基DIOXITOL 112-34-5
甲基PROXITOL 107-98-2
甲基DIPROXITOL 34590-94-8
醋酸甲酯PROXITOL 108-65-6
乙基PROXITOL 1569年2月4日
异丙基OXITOL 109-59-1
图二：涂料
乙二醇醚和醋酸盐是有效的
在许多表面涂层技术，包括;
●高固体涂料，低
●水性乳液
●水还原涂料
至于'真溶剂乙二醇醚是能够
解散所有许多树脂的比例，
而且特别是在促进流动有用
属性。他们还鼓励良好的光泽
并通过维持树脂（的电影属性）
在溶液中形成的整个电影
过程。
乙二醇醚也扮演着重要组成部分
会议挥发性有机化合物的规定。其高溶剂
权力意味着他们可以在使用高
固体涂料维持低粘度
性能和应用性能。
高沸点乙二醇醚及其酯类
在水性高效成膜溶剂
乳胶乳液。他们减少成膜
温度，使树脂将更难
制定成常温固化涂料。
醋酸甲酯PROXITOL，而这
不包含羟基功能，是一种理想
溶剂高固体双组分
聚氨酯涂料，因为它不
干预xx的反应。
油墨
乙二醇醚组合及其他
溶剂可用于实现
正确的蒸发率，
流平性能，水
相容性和溶解性
用于油墨配方。他们
也可以用来调整
表面张力和粘度，
促进深的，甚至渗透
油墨软基板。
其他电子产品
覆铜箔层压胶粘剂
层板中间体
光敏燃油添加剂
制药
化妆品
工业过程
油田化学品
挖掘化学品
农业化学
纺织和皮革染料
乙二醇醚的用途有多个完
工业现金等价物
DOWANOL ®电子束（保函）
DOWANOL ®数据库（BDG）
DOWANOL ®下午，ARCOSOL ®下午
DOWANOL ®的DPM，ARCOSOLV ®的DPM
DOWANOL ® PMA的，ARCOSOLV ® PMA的
ARCOSOLV ®聚乙烯（EP）的
壳产品范围
壳牌化工乙二醇范围
以自己的勤劳醚当量， 产品名称挥发性有机化合物*致畸毒物风险/安全警语
丁基OXITOL是否R20/21/22，36/38，S24/25
丁基DIOXITOL否否R36的，S24/26
甲基PROXITOL是否奥迪R10，S24号
甲基DIPROXITOL是否S24号
醋酸甲酯PROXITOL是否奥迪R10，36，S25图形
乙基PROXITOL是否奥迪R10，S24号
异丙基OXITOL是否R10赛车，20/21，36，S24/25
图三：健康安全环境规格
健康与安全
ethylenebased相对于较短的烷基链
乙二醇醚，产品在壳牌
产品组合没有证据显示
生殖毒性（参见图3）。这
优势提供机会
短链烷基取代乙烯为基础的
在配方乙二醇醚在人体
暴露不能被排除在外。在许多
情况下，可以直接作出
替代，与成本效益和
相当的性能 - 例如乙基
乙二醇甲醚可代替甲基
PROXITOL。在更复杂的应用程序
重新使用这样的程序
壳牌BlendPro™可用于查找
{zj0}替代品。材料的安全
数据表提供额外
信息的健康，安全和
壳聚乙二醇醚类的监管地位的
可用于OXITOL和PROXITOL
产品范围。
BlendPro™是一个功能强大的溶剂改写
软件开发由壳牌
让用户来计算溶剂混合溶剂
属性并重新融合在一起
就技术性能和/或费用。
*挥发性有机物：一种有机化合物，在25 ° C间有
在0.01千帕或以上的蒸气压力。我们的生产能力，随着
销售，营销和物流，是面向
为全球市场，并满足
乙二醇醚日益增长的需求。
建造一个新的{sjj}工厂
在佩尔尼斯在荷兰有更多的
我们的一倍以上的潜在产出
乙二醇醚。该工厂位于10万吨
旁边另一个五五克拉多用途
工厂，而在北美，我们有
另外30万吨乙二醇醚的EO
能力。这背后是一个生产
强大的原料供应链，主要
支持我们自己的环氧丙烷
环氧乙烷和植物，其中
确保供应安全
客户。
全球能力进一步资料
欲了解更多有关PROXITOL和OXITOL信息
乙二醇醚范围，请联系您的贝壳
化学品的代表，或e - mail给我们的：

访问我们的网站：

本出版物中的信息就是，我们的知识，真正的{zj0}
和准确的，但任何建议或意见可能
作都没有保证，因为使用的条件，是无法
我们的控制。此外，包含的任何条款都不得被解释
作为推荐使用与现有的专利冲突的任何产品
其涵盖的任何材料或使用。
每个公司作出了皇家荷兰/壳牌集团
公司是一个独立的实体，有自己独立的身份。
资深大律师:3053 - 01

Glycol ethers and their esters are
colourless, stable liquids of high boiling
point and mild odour. With both an ether
group and an alcohol or ester group in
the same molecule, they can mix with
both water and other solvents, and
combine powerful dissolving
characteristics with low volatility.
This combination of properties gives
glycol ethers some key performance
characteristics for solvent-based systems
including:
● Miscibility with water
● Compatibility with a
wide range of polar
and non-polar solvents
● High solvent power
● Low volatility
● Mild odour
● Coalescence
Shell Glycol Ethers:
OXITOL* and PROXITOL*
* OXITOL and PROXITOL are trademarks of
the Royal Dutch/Shell Group of companies.
Versatile, high performance solvents designed to meet the
increasing technical and environmental demands of solventbased
formulations. Glycol ethers are ideally suited to new
low aromatic, high solid and waterborne technologies driven
by legislation and consumer requirements.

Cosmetics/personal care
The solvent and coupling properties of
glycol ethers are utilised in many cosmetic
and toiletry formulations. They can be
used to stabilise emulsions used in lotions,
preventing the active ingredient particles
from dropping out of suspension.
This helps to maintain the aesthetic
appearance of the product and can
increase shelf-life. They can also
be used to improve water repellency
in products such as sun screens.
Industrial and household cleaners
Glycol ethers can be used in all types of
cleaners. They reduce surface tension and
are excellent coupling agents. Working in
conjunction with a surfactant, they facilitate
wetting of the surface, penetration of the
soil, and help to suspend the soil in water
until it is wiped or rinsed away.
The choice of glycol ether depends on the
type of cleaning application, the nature of
the soil, and the solubility and evaporation
rate required. Blends of glycol ethers and
surfactants can be used to optimise
cleaning performance and efficiency.
Coatings Cleaners & Inks
Automotive All-Purpose
Industrial Maintenance Glass
Coil Oven
Appliance & Equipment Industrial
Lacquer & Stains Household
Architectural Gravure
Marine Flexograph
Aerospace Screen Printing
Plastic Primer Offset Printing
Resin Formulations
Colorants
Thinners
Speciality Paints
FIGURE ONE:
Key applications
Glycol ethers can be used in a wide range of applications
and across a broad range of industry sectors (see Figure1).
Among the key application areas are:
Shell product Cas. No.
Butyl OXITOL 111-76-2
Butyl DIOXITOL 112-34-5
Methyl PROXITOL 107-98-2
Methyl DIPROXITOL 34590-94-8
Methyl PROXITOL acetate 108-65-6
Ethyl PROXITOL 1569-02-4
Isopropyl OXITOL 109-59-1
FIGURE TWO:

Coatings
Glycol ethers and their acetates are effective
in many surface coating technologies including;
● high and low solid coatings
● waterborne emulsions
● water-reducible coatings
As ‘true solvents’ glycol ethers are able
to dissolve many resins in all proportions,
and are particularly useful in promoting flow
properties. They also encourage good gloss
and film properties by maintaining the resin(s)
in solution throughout the film formation
process.
Glycol ethers also play an important part in
meeting VOC regulations. Their high solvent
power means they can be used in high
solids coatings to maintain low viscosity
and application performance properties.
Higher boiling glycol ethers and their esters
are efficient coalescent solvents in waterborne
latex emulsions. They reduce film formation
temperatures, allowing harder resins to be
formulated into ambient cure coatings.
Methyl PROXITOL acetate, which does
not contain a hydroxyl function, is an ideal
solvent for high solids, two-component
polyurethane coatings, as it does not
interfere with the curing reactions.
Inks
Combinations of glycol ethers and other
solvents can be used to achieve
the right evaporation rates,
levelling properties, water
miscibility and solubility
for ink formulations. They
can also be used to adjust
surface tension and viscosity,
promoting deep and even penetration
of inks on soft substrates.
Electronics Other
Copper Clad laminating Adhesives
Laminates Intermediates
Photoresistors Fuel Additives
Pharmaceuticals
Cosmetics
Industrial Processes
Oil Field Chemicals
Mining Chemicals
Agricultural Chemicals
Textile & Leather Dyes
GLYCOL ETHERS HAVE MULTIPLE END USES
Industry Equivalents
DOWANOL® EB (BG)
DOWANOL® DB (BDG)
DOWANOL® PM, ARCOSOL® PM
DOWANOL® DPM, ARCOSOLV® DPM
DOWANOL® PMA, ARCOSOLV® PMA
ARCOSOLV® PE (EP)
SHELL PRODUCT RANGE
The Shell Chemicals range of glycol
ethers with their industry equivalent,
where applicable.

Product name VOC* Teratogenic toxicant Risk/safety phrases
Butyl OXITOL Yes No R20/21/22, 36/38, S24/25
Butyl DIOXITOL No No R36, S24/26
Methyl PROXITOL Yes No R10, S24
Methyl DIPROXITOL Yes No S24
Methyl PROXITOL acetate Yes No R10, 36, S25
Ethyl PROXITOL Yes No R10, S24
Isopropyl OXITOL Yes No R10, 20/21, 36, S24/25
FIGURE THREE: HSE SPECIFICATIONS
Health and safety
In contrast to shorter alkyl-chain ethylenebased
glycol ethers, products in the Shell
product portfolio show no evidence of
reproductive toxicity (see Figure 3). This
advantage provides opportunities for
replacing short alkyl chain ethylene-based
glycol ethers in formulations where human
exposure cannot be excluded. In many
cases it is possible to make a direct
substitution, with cost effectiveness and
equivalent performance - for example ethyl
glycol ether can be replaced by Methyl
PROXITOL. In more complex applications
reformulation using a programme such
as Shell BlendPro™ can be used to find
the optimum replacement. Material safety
data sheets which provide additional
information about the health, safety and
regulatory status of Shell glycol ethers are
available for the OXITOL and PROXITOL
product ranges.
BlendPro™ is a powerful solvent reformulation
software programme developed by Shell to
enable solvents users to calculate solvent blend
properties and to reformulate blends with
respect to technical performance and/or costs.
* VOC: an organic compound having at 25°C
a vapour pressure of 0.01 kPa or more.Our production capacity, along with
sales, marketing and logistics, is geared
to serve global markets, and to satisfy
growing demand for glycol ethers.
Construction of a new world-scale plant
at Pernis in the Netherlands has more
than doubled our potential output of
glycol ethers. The 100 kt plant sits
alongside another 55 kt multi-purpose
plant, while in North America we have
an additional 30 kt of EO glycol ethers
capacity. This production is backed by a
strong feedstock chain, primarily
supported by our own propylene oxide
and ethylene oxide plants, which
ensures security of supply for
customers.
Global capacityFurther information
For more information on the PROXITOL and OXITOL
ranges of glycol ethers please contact your Shell
Chemicals representative, or e-mail us at:
vanoil@vanoil.com.cn
Visit our website at: www.shell.com/chemicals
Information in this publication is, to the best of our knowledge, true
and accurate, but any recommendations or suggestions which may
be made are without guarantee, since the conditions of use are beyond
our control. Furthermore, nothing contained herein shall be construed
as a recommendation to use any product in conflict with existing patents
covering any material or its use.
Each of the companies which make up the Royal Dutch/Shell Group
of companies is an independent entity and has its own separate identity.
SC:3053-01